Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides

ABSTRACT

Fungicidal mixtures, comprising as active components
     1) at least one 1-methylpyrazol-4-ylcarboxanilides of the formula I   

     
       
         
         
             
             
         
       
         
         
           
             where X=O or S, R 1 =C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl, R 2 =hydrogen or halogen, R 3 , R 4  and R 5 =independently of one another cyano, nitro, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkoxy or C 1 -C 4 -alkylthio; 
             and 
           
         
         2) at least one active compound II, selected from the active compound groups A) to F):
       A) azoles;   B) strobilurins;   C) carboxamides;   D) heterocyclic compounds;   E) carbamates;   F) other fungicides;
 
in a synergistically effective amount, methods for controlling harmful fungi using mixtures of at least one compound I and at least one active compound II and the use of the compound(s) I with active compounds II for preparing such mixtures, and also compositions and seed comprising such mixtures.

This application is a National Stage application of InternationalApplication No. PCT/EP2006/064907, filed Aug. 1, 2006, the entirecontents of which is hereby incorporated herein by reference. Thisapplication also claims the benefit under 35 U.S.C. §119 of GermanPatent Application No. 102005037677.0, filed Aug. 5, 2005 and EuropeanPatent Application No. 06101198.7, filed Feb. 2, 2006.

The present invention relates to fungicidal mixtures comprising, asactive components,

-   1) at least one 1-methylpyrazol-4-ylcarboxanilides of the formula I

-   -   in which the substituents are as defined below:    -   X is oxygen or sulfur;    -   R¹ is C₁-C₄-alkyl or C₁-C₄-haloalkyl;    -   R² is hydrogen or halogen;    -   R³, R⁴ and R⁵ independently of one another are cyano, nitro,        halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy,        C₁-C₄-haloalkoxy or C₁-C₄-alkylthio;        and

-   2) at least one active compound II selected from the active compound    groups A) to F):    -   A) azoles selected from the group consisting of bitertanol,        bromuconazole, cyproconazole, difenoconazole, diniconazole,        enilconazole, epoxiconazole, fluquinconazole, fenbuconazole,        flusilazole, flutriafol, hexaconazole, imibenconazole,        ipconazole, metconazole, myclobutanil, penconazole,        propiconazole, prothioconazole, simeconazole, triadimefon,        triadimenol, tebuconazole, tetraconazole, triticonazole,        prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid,        benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam,        etridiazole and hymexazole;    -   B) strobilurins selected from the group consisting of        azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin,        kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin,        pyraclostrobin, trifloxystrobin, enestroburin, methyl        (2-chloro-5-[1-(3-methyl-benzyloxyimino)ethyl]benzyl)carbamate,        methyl        (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate        and methyl        2-(ortho-(2,5-dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate;    -   C) carboxamides selected from the group consisting of carboxin,        benalaxyl; boscalid, fenhexamid, flutolanil, furametpyr,        mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin,        penthiopyrad, thifluzamide, tiadinil,        -   3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide,            dimethomorph, flumorph, flumetover, fluopicolide            (picobenzamid), zoxamide, carpropamid, diclocymet,            mandipropamid,            N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide,            N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide,            methyl            3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propionate,            compounds of the formula III

-   -   -   in which R⁴ is methyl or ethyl,        -   N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,            N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,            N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,            N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide,            N-(3′,4′-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-ylcarboxamide            and N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide;

    -   D) heterocyclic compounds selected from the group consisting of        fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol,        ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine,        fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph,        tridemorph, fenpropidin, iprodione, procymidone, vinclozolin,        famoxadone, fenamidone, octhilinone, probenazole,        5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine,        -   anilazine, diclomezine, pyroquilon, proquinazid,            tricyclazole, the compound of the formula IV            (2-butoxy-6-iodo-3-propylchromen-4-one)

-   -   -   acibenzolar-S-methyl, captafol, captan, dazomet, folpet,            fenoxanil, quinoxyfen and        -   N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide            of the formula V

-   -   E) carbamates selected from the group consisting of mancozeb,        maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram,        diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb,        4-fluorophenyl        N-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)carbamate, methyl        3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propanoate        of the formula VI

-   -   -   and carbamate oxime ethers of the formula VII

-   -   -   in which Z is N or CH;

    -   F) other fungicides selected from the group consisting of        guanidine, dodine, iminoctadine, guazatine, antibiotics:        kasugamycin, streptomycin, polyoxin, validamycin A, nitrophenyl        derivatives: binapacryl, dinocap, dinobuton, sulfur-containing        heterocyclyl compounds: dithianon, isoprothiolane,        organometallic compounds: fentin salts such as fentin acetate,        organophosphorus compounds: edifenphos, iprobenfos, fosetyl,        fosetyl-aluminum, phosphorous acid and its salts, pyrazophos,        tolclofos-methyl,        -   organochlorine compounds: chlorothalonil, dichlofluanid,            flusulfamide, hexachlorobenzene, phthalide, pencycuron,            quintozene, thiophanate-methyl, tolylfluanid,        -   inorganic active compounds: Bordeaux mixture, copper            acetate, copper hydroxide, copper oxychloride, basic copper            sulfate, sulfur, others: cyflufenamid, cymoxanil,            dimethirimol, ethirimol, furalaxyl, metrafenone and            spiroxamine;            in a synergistically effective amount.

Moreover, the invention relates to a method for controlling harmfulfungi using a mixture of at least one compound I and at least one of theactive compounds II, to the use of the compound(s) I with activecompound(s) II for preparing such mixtures, and also to compositions andseed comprising such mixtures.

The 1-methylpyrazol-4-ylcarboxanilides of the formula I, referred toabove as component 1), their preparation and their action againstharmful fungi are known from the literature (cf., for example, EP-A 545099, EP-A 589 301 and WO 99/09013), or they can be prepared in themanner described therein.

The compounds I in which X is sulfur can be prepared, for example, bysulfurizing the corresponding compounds I in which X is oxygen (cf. e.g.D. Petrova & K. Jakobcic, Croat. Chem. Acta 48, 49 (1976) and WO01/42223).

However, the known 1-methylpyrazol-4-ylcarboxanilides of the formula Iare, in particular at low application rates, not entirely satisfactory.

The active compounds II mentioned above as component 2, theirpreparation and their action against harmful fungi are generally known(cf., for example, http://www.hclrss.demon.co.uk/index.html); they arecommercially available.

-   Benalaxyl, methyl N-(phenylacetyl)-N-(2,6-xylyl)-DL-alaninate (DE 29    03 612);-   metalaxyl, methyl N-(methoxyacetyl)-N-(2,6-xylyl)-DL-alaninate (GB    15 00 581);-   ofurace, (RS)-α-(2-chloro-N-2,6-xylylacetamido)-γ-butyrolactone [CAS    RN 58810-48-3];-   oxadixyl;    N-(2,6-dimethylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)acetamide    (GB 20 58 059);-   aldimorph, “4-alkyl-2,5(or 2,6)-dimethylmorpholine”, comprising    65-75% of 2,6-dimethylmorpholine and 25-35% of    2,5-dimethylmorpholine, comprising more than 85% of 4-dodecyl-2,5(or    2,6)-dimethylmorpholine, where “alkyl” also includes octyl, decyl,    tetradecyl and hexadecyl, with a cis/trans ratio of 1:1 [CAS RN    91315-15-0];-   dodine, 1-dodecylguanidinium acetate (Plant Dis. Rep., Vol. 41, p.    1029 (1957));-   dodemorph, 4-cyclododecyl-2,6-dimethylmorpholine (DE-A 1198125);-   fenpropimorph,    (RS)-cis-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethyl-morpholine    (DE-A 27 52 096);-   fenpropidin,    (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine (DE-A 27 52    096);-   guazatine, mixture of the reaction products from the amidation of    technical grade iminodi(octamethylene)diamine, comprising various    guanidines and polyamines [CAS RN 108173-90-6];-   iminoctadine, 1,1′-iminodi(octamethylene)diguanidine (Congr. Plant    Pathol., 1., p. 27 (1968);-   spiroxamine, (8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-yl)diethylamine    (EP-A 281 842);-   tridemorph, 2,6-dimethyl-4-tridecylmorpholine (DE-A 11 64 152);-   pyrimethanil, 4,6-dimethylpyrimidin-2-ylphenylamine (DD-A 151 404);-   mepanipyrim, (4-methyl-6-prop-1-ynylpyrimidin-2-yl)phenylamine (EP-A    224 339);-   cyprodinil, (4-cyclopropyl-6-methylpyrimidin-2-yl)phenylamine (EP-A    310 550);-   cycloheximide,    4-{(2R)-2-[(1S,3S,5S)-3,5-dimethyl-2-oxocyclohexyl]-2-hydroxyethyl}piperidine-2,6-dione    [CAS RN 66-81-9];-   griseofulvin,    7-chloro-2′,4,6-trimethoxy-6′-methylspiro[benzofuran-2(3H),    1′-cyclohex-2′-ene]-3,4′-dione [CAS RN 126-07-8];-   kasugamycin,    3-O-[2-amino-4-[(carboxyiminomethyl)amino]-2,3,4,6-tetradeoxy-α-D-arabino-hexopyranosyl]-D-chiro-inositol    [CAS RN 6980-18-3];-   natamycin,    (8E,14E,16E,18E,20E)-(1R,3S,5R,7R,12R,22R,24S,25R,26S)-22-(3-amino-3,6-dideoxy-β-D-mannopyranosyloxy)-1,3,26-trihydroxy-12-methyl-10-oxo-6,11,28-trioxatricyclo[22.3.1.0^(5,7)]octacosa-8,14,16,18,20-pentaene-25-carboxylic    acid [CAS RN 7681-93-8];-   polyoxin,    5-(2-amino-5-O-carbamoyl-2-deoxy-L-xylonamido)-1-(5-carboxy-1,2,3,4-tetrahydro-2,4-dioxopyrimidin-1-yl)-1,5-dideoxy-β-D-allofuranuronic    acid [CAS RN 22976-86-9];-   streptomycin,    1,1′-{1-L-(1,3,5/2,4,6)-4-[5-deoxy-2-O-(2-deoxy-2-methylamino-α-L-glucopyranosyl)-3-C-formyl-α-L-lyxofuranosyloxy]-2,5,6-trihydroxycyclohex-1,3-ylene}diguanidine    (J. Am. Chem. Soc. Vol. 69, p. 1234 (1947));-   bitertanol,    β-([1,1′-biphenyl]-4-yloxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol    (DE-A 23 24 020);-   bromuconazole,    1-[[4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl]methyl]-1H-1,2,4-triazole    (Proc. 1990 Br. Crop. Prot. Conf.—Pests Dis. Vol. 1, p. 459);-   cyproconazole,    2-(4-chlorophenyl)-3-cyclopropyl-1-[1,2,4]triazol-1-ylbutan-2-ol    (U.S. Pat. No. 4,664,696);-   difenoconazole,    1-{2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-[1,3]dioxolan-2-ylmethyl}-1H-[1,2,4]triazole    (GB-A 2 098 607);-   diniconazole,    (βE)-β-[(2,4-dichlorophenyl)methylene]-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol    (Noyaku Kagaku, 1983, Vol. 8, p. 575);-   enilconazole (imazalil),    1-[2-(2,4-dichlorophenyl)-2-(2-propenyloxy)ethyl]-1H-imidazole    (Fruits, 1973, Vol. 28, p. 545);-   epoxiconazole,    (2RS,3SR)-1-[3-(2-chlorophenyl)-2,3-epoxy-2-(4-fluorophenyl)propyl]-1H-1,2,4-triazole    (EP-A 196 038);-   fenbuconazole,    α-[2-(4-chlorophenyl)ethyl]-α-phenyl-1H-1,2,4-triazole-1-propanenitrile    (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 33);-   fluquinconazole,    3-(2,4-dichlorophenyl)-6-fluoro-2-[1,2,4]-triazol-1-yl-3H-quinazolin-4-one    (Proc. Br. Crop Prot. Conf.—Pests Dis., 5-3, 411 (1992));-   flusilazole,    1-{[bis(4-fluorophenyl)methylsilanyl]methyl}-1H-[1,2,4]triazole    (Proc. Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 413 (1984));-   flutriafol,    α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol    (EP-A 15 756);-   hexaconazole, 2-(2,4-dichlorophenyl)-1-[1,2,4]triazol-1-ylhexan-2-ol    (CAS RN 79983-71-4);-   ipconazole,    2-[(4-chlorophenyl)methyl]-5-(1-methylethyl)-1-(1H-1,2,4-triazol-1-yl-methyl)cyclopentanol    (EP-A 267 778),-   metconazole,    5-(4-chlorobenzyl)-2,2-dimethyl-1-[1,2,4]triazol-1-ylmethylcyclopentanol    (GB 857 383);-   myclobutanil,    2-(4-chlorophenyl)-2-[1,2,4]triazol-1-ylmethylpentanenitrile (CAS RN    88671-89-0);-   penconazole, 1-[2-(2,4-dichlorophenyl)pentyl]-1H-[1,2,4]triazole    (Pesticide Manual, 12th Ed. 2000, p. 712);-   propiconazole,    1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole    (BE 835 579);-   prochloraz,    N-(propyl-[2-(2,4,6-trichlorophenoxy)ethyl])imidazole-1-carboxamide    (U.S. Pat. No. 3,991,071);-   prothioconazole,    2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro[1,2,4]triazole-3-thione    (WO 96/16048);-   simeconazole,    α-(4-fluorophenyl)-α-[(trimethylsilyl)methyl]-1H-1,2,4-triazole-1-ethanol    [CAS RN 149508-90-7],-   tebuconazole,    1-(4-chlorophenyl)-4,4-dimethyl-3-[1,2,4]triazol-1-ylmethylpentan-3-ol    (EP-A 40 345);-   tetraconazole,    1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]-1H-1,2,4-triazole    (EP-A 234 242);-   triadimefon,    1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone    (BE 793 867);-   triadimenol,    β-(4-chlorophenoxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol    (DE-A 23 24 010);-   triflumizol,    (4-chloro-2-trifluoromethylphenyl)-(2-propoxy-1-[1,2,4]triazol-1-ylethylidene)-amine    (JP-A 79/1.19 462);-   triticonazole,    (5E)-5-[(4-chlorophenyl)methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol    (FR 26 41 277);-   iprodione,    N-isopropyl-3-(3,5-dichlorophenyl)-2,4-dioxoimidazolidine-1-carboxamide    (GB 13 12 536);-   myclozolin,    (RS)-3-(3,5-dichlorophenyl)-5-methoxymethyl-5-methyl-1,3-oxazolidine-2,4-dione    [CAS RN 54864-61-8];-   procymidone,    N-(3,5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide    (U.S. Pat. No. 3,903,090);-   vinclozolin,    3-(3,5-dichlorophenyl)-5-methyl-5-vinyloxazolidine-2,4-dione (DE-A    22 07 576);-   ferbam, iron(3+) dimethyldithiocarbamate (U.S. Pat. No. 1,972,961);-   nabam, disodium ethylenebis(dithiocarbamate) (U.S. Pat. No.    2,317,765);-   maneb, manganese ethylenebis(dithiocarbamate) (U.S. Pat. No.    2,504,404);-   mancozeb, manganese ethylenebis(dithiocarbamate) polymer complex    zinc salt (GB 996 264);-   metam, methyldithiocarbaminic acid (U.S. Pat. No. 2,791,605);-   metiram, zinc ammoniate ethylenebis(dithiocarbamate) (U.S. Pat. No.    3,248,400);-   propineb, zinc propylenebis(dithiocarbamate) polymer (BE 611 960);-   polycarbamate,    bis(dimethylcarbamodithioato-κS,κS′)[μ-[[1,2-ethanediylbis[carbamodithioato-κS,κS′]](2−)]]di[zinc]    [CAS RN 64440-88-6];-   thiram, bis(dimethylthiocarbamoyl)disulfide (DE-A 642 532);-   ziram, dimethyldithiocarbamate [CAS RN 137-30-4];-   zineb, zinc ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,457,674);-   anilazine, 4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazine-2-amine    (U.S. Pat. No. 2,720,480);-   benomyl, N-butyl-2-acetylaminobenzimidazole-1-carboxamide (U.S. Pat.    No. 3,631,176);-   boscalid, 2-chloro-N-(4′-chlorobiphenyl-2-yl)nicotinamide (EP-A 545    099);-   carbendazim, methyl (1H-benzimidazol-2-yl)carbamate (U.S. Pat. No.    3,657,443);-   carboxin, 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiine-3-carboxamide    (U.S. Pat. No. 3,249,499);-   oxycarboxin, 5,6-dihydro-2-methyl-1,4-oxathiine-3-carboxanilide    4,4-dioxide (U.S. Pat. No. 3,399,214);-   cyazofamid,    4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1H-imidazole-1-sulfon-amide    (CAS RN 120116-88-3];-   dazomet, 3,5-dimethyl-1,3,5-thiadiazinane-2-thione (Bull. Soc. Chim.    Fr. Vol. 15, p. 891 (1897));-   diflufenzopyr,    2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinic acid [CAS    RN 109293-97-2];-   dithianon,    5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin-2,3-dicarbonitrile    (GB 857 383);-   famoxadone,    (RS)-3-anilino-S-methyl-5-(4-phenoxyphenyl)-1,3-oxazolidine-2,4-dione    [CAS RN 131807-57-3];-   fenamidone,    (S)-1-anilino-4-methyl-2-methylthio-4-phenylimidazolin-5-one [CAS RN    161326-34-7];-   fenarimol,    α-(2-chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol (GB 12 18    623);-   fuberidazole, 2-(2-furanyl)-1H-benzimidazole (DE-A 12 09 799);-   flutolanil, α,α,α-trifluoro-3′-isopropoxy-o-toluanilide (JP    1104514);-   furametpyr,    5-chloro-N-(1,3-dihydro-1,1,3-trimethyl-4-isobenzofuranyl)-1,3-dimethyl-1H-pyrazole-4-carboxamide    [CAS RN 123572-88-3];-   isoprothiolane, diisopropyl 1,3-dithiolan-2-ylidenemalonate (Proc.    Insectic. Fungic. Conf. 8. Vol. 2, p. 715 (1975));-   mepronil, 3′-isopropoxy-o-toluanilide (U.S. Pat. No. 3,937,840);-   nuarimol, α-(2-chlorophenyl)-α-(4-fluorophenyl)-5-pyrimidinemethanol    (GB 12 18 623);-   fluopicolide (picobenzamid),    2,6-dichloro-N-(3-chloro-5-trifluoromethylpyridin-2-ylmethyl)benzamide    (WO 99/42447);-   probenazole, 3-allyloxy-1,2-benzothiazole 1,1-dioxide (Agric. Biol.    Chem. Vol. 37, p. 737 (1973));-   proquinazid, 6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one (WO    97/48684);-   pyrifenox, 2′,4′-dichloro-2-(3-pyridyl)acetophenone    (EZ)-O-methyloxime (EP 49 854);-   pyroquilon, 1,2,5,6-tetrahydropyrrolo[3,2,1-ij]quinolin-4-one (GB    139 43 373) quinoxyfen, 5,7-dichloro-4-(4-fluorophenoxy)quinoline    (U.S. Pat. No. 5,240,940);-   silthiofam,    N-allyl-4,5-dimethyl-2-(trimethylsilyl)thiophene-3-carboxamide [CAS    RN 175217-20-6];-   thiabendazole, 2-(1,3-thiazol-4-yl)benzimidazole (U.S. Pat. No.    3,017,415);-   thifluzamide,    2′,6′-dibromo-2-methyl-4′-trifluoromethoxy-4-trifluoromethyl-1,3-thiazole-5-carboxanilide    [CAS RN 130000-40-7];-   thiophanate-methyl,    1,2-phenylenebis(iminocarbonothioyl)bis(dimethylcarbamate) (DE-A 19    30-540);-   tiadinil, 3′-chloro-4,4′-dimethyl-1,2,3-thiadiazole-5-carboxanilide    [CAS RN 223580-51-6];-   tricyclazole, 5-methyl-1,2,4-triazolo[3,4-b][1,3]benzothiazole [CAS    RN 41814-78-2];-   triforine,    N,N′-{piperazine-1,4-diylbis[(trichloromethyl)methylene]}diformamide    (DE-A 19 01 421);-   5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine    (WO 98/46607);-   Bordeaux mixture, mixture of CuSO₄×₃Cu(OH)₂×3CaSO₄ [CAS RN    8011-63-0] copper acetate, Cu(OCOCH₃)₂ [CAS RN 8011-63-0];-   copper oxychloride, CU₂Cl(OH)₃ [CAS RN 1332-40-7];-   basic copper sulfate, CuSO₄ [CAS RN 1344-73-6];-   binapacryl, (RS)-2-sec-butyl-4,6-dinitrophenyl 3-methylcrotonate    [CAS RN 485-31-4];-   dinocap, mixture of 2,6-dinitro-4-octylphenylcrotonate and    2,4-dinitro-6-octyl-phenylcrotonate, where “octyl” is a mixture of    1-methylheptyl, 1-ethylhexyl and 1-propylpentyl (U.S. Pat. No.    2,526,660);-   dinobuton, (RS)-2-sec-butyl-4,6-dinitrophenyl isopropyl carbonate    [CAS RN 973-21-7];-   nitrothal-isopropyl, diisopropyl 5-nitroisophthalate (Proc. Br.    Insectic. Fungic. Conf. 7., Vol. 2, p. 673 (1973));-   fenpiclonil, 4-(2,3-dichlorophenyl)-1H-pyrrole-3-carbonitrile (Proc.    1988 Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 65);-   fludioxonil,    4-(2,2-difluorobenzo[1,3]dioxol-4-yl)-1H-pyrrole-3-carbonitrile (The    Pesticide Manual, publ. The British Crop Protection Council, 10th    ed. 1995, p. 482);-   acibenzolar-S-methyl, methyl 1,2,3-benzothiadiazole-7-carbothioate    [CAS RN 135158-54-2];-   flubenthiavalicarb (benthiavalicarb), isopropyl    {(S)-1-[(1R)-1-(6-fluorobenzothiazol-2-yl)-ethylcarbamoyl]-2-methylpropyl}carbamate    (JP-A 09/323,984);-   carpropamid,    2,2-dichloro-N-[1-(4-chlorophenyl)ethyl]-1-ethyl-3-methylcyclopropane-carboxamide    [CAS RN 104030-54-8];-   chlorothalonil, 2,4,5,6-tetrachloroisophthalonitrile (U.S. Pat. No.    3,290,353);-   cyflufenamid,    (Z)—N-[α-(cyclopropylmethoxyimino)-2,3-difluoro-6-(trifluoromethyl)benzyl]-2-phenylacetamide    (WO 96/19442);-   cymoxanil, 1-(2-cyano-2-methoxyiminoacetyl)-3-ethylurea (U.S. Pat.    No. 3,957,847);-   diclomezine, 6-(3,5-dichlorophenyl-p-tolyl)pyridazin-3(2H)-one (U.S.    Pat. No. 4,052,395) diclocymet,    (RS)-2-cyano-N—[(R)-1-(2,4-dichlorophenyl)ethyl]-3,3-dimethylbutyramide    [CAS RN 139920-32-4];-   diethofencarb, isopropyl 3,4-diethoxycarbanilate (EP-A 78 663);-   edifenphos, O-ethyl S,S-diphenyl phosphorodithioate (DE-A 14 93 736)    ethaboxam,    N-(cyano-2-thienylmethyl)-4-ethyl-2-(ethylamino)-5-thiazolecarboxamide    (EP-A 639 574);-   fenhexamid,    N-(2,3-dichloro-4-hydroxyphenyl)-1-methylcyclohexanecarboxamide    (Proc. Br. Crop Prot. Conf.—Pests Dis., 1998, Vol. 2, p. 327);-   fentin-acetate, triphenyltin (U.S. Pat. No. 3,499,086);-   fenoxanil,    N-(1-cyano-1,2-dimethylpropyl)-2-(2,4-dichlorophenoxy)propanamide    (EP-A 262 393);-   ferimzone,    (Z)-2′-methylacetophenone-4,6-dimethylpyrimidin-2-ylhydrazone [CAS    RN 89269-64-7];-   fluazinam,    3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl]-5-(trifluoromethyl)-2-pyridinamine    (The Pesticide Manual, publ. The British Crop Protection Council,    10th ed. (1995), p. 474);-   fosetyl, fosetyl-aluminum, ethylphosphonate (FR 22 54 276);-   iprovalicarb, isopropyl    [(1S)-2-methyl-1-(1-p-tolylethylcarbamoyl)propyl]carbamate (EP-A 472    996);-   hexachlorobenzene (C. R. Seances Acad. Agric. Fr., Vol. 31, p. 24    (1945));-   mandipropamid,    (RS)-2-(4-chlorophenyl)-N-[3-methoxy-4-(prop-2-ynyloxy)phenethyl]-2-(prop-2-ynyloxy)acetamide    (WO 03/042166);-   metrafenone,    3′-bromo-2,3,4,6′-tetramethoxy-2′,6-dimethylbenzophenone (U.S. Pat.    No. 5,945,567);-   pencycuron, 1-(4-chlorobenzyl)-1-cyclopentyl-3-phenylurea (DE-A 27    32 257);-   penthiopyrad,    (RS)—N-[2-(1,3-dimethylbutyl)-3-thienyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide    (JP 10/130,268);-   propamocarb, isopropyl 3-(dimethylamino)propylcarbamate (DE-A 15 67    169);-   phthalide (DE-A 16 43 347);-   toloclofos-methyl, O-2,6-dichloro-p-tolyl O,O-dimethyl    phosphorothioate (GB 14 67 561);-   quintozene, pentachloronitrobenzene (DE-A 682 048);-   zoxamide,    (RS)-3,5-dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-p-toluamide    [CAS RN 156052-68-5];-   captafol,    N-(1,1,2,2-tetrachloroethylthio)cyclohex-4-ene-1,2-dicarboximide    (Phytopathology, Vol. 52, p. 754 (1962));-   captan, N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide    (U.S. Pat. No. 2,553,770);-   dichlofluanid,    N-dichlorofluoromethylthio-N′,N′-dimethyl-N-phenylsulfamide (DE-A 11    93 498);-   folpet, N-(trichloromethylthio)phthalimide (U.S. Pat. No.    2,553,770);-   tolylfluanid,    N-dichlorofluoromethylthio-N′,N′-dimethyl-N-p-tolylsulfamide (DE-A    11 93 498);-   dimethomorph,    3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-yl-propenone    (EP-A 120 321);-   flumetover,    2-(3,4-dimethoxyphenyl)-N-ethyl-α,α,α-trifluoro-N-methyl-p-toluamide    [AGROW no. 243, 22 (1995)];-   flumorph,    3-(4-fluorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-ylpropenone    (EP-A 860 438);-   N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,-   N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,    N-(4′-chloro-3′-7-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide    (WO 03/66610);-   N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide    and    N-(3′,4′-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide    (WO 03/70705);-   N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide (WO    99/24413);-   N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide,    N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide    (WO 04/49804);-   3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine (EP-A    10 35 122);-   2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103);-   N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfon-amide    (EP-A 10 31 571);-   methyl    (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate,-   methyl    (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate    (EP-A 12 01 648);-   methyl    3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propionate    (EP-A 10 28 125);-   azoxystrobin, methyl    2-{2-[6-(2-cyano-1-vinylpenta-1,3-dienyloxy)pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate    (EP-A 382 375),-   dimoxystrobin,    (E)-2-(methoxyimino)-N-methyl-2-[α-(2,5-xylyloxy)-o-tolyl]acetamide    (EP-A 477 631);-   fluoxastrobin,    (E)-{2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yloxy]phenyl}(5,6-dihydro-1,4,2-dioxazin-3-yl)methanone    O-methyloxime (WO 97/27189);-   kresoxim-methyl, methyl    (E)-methoxyimino[α-(o-tolyloxy)-o-tolyl]acetate (EP-A 253 213);-   metominostrobin,    (E)-2-(methoxyimino)-N-methyl-2-(2-phenoxyphenyl)acetamide (EP-A 398    692);-   orysastrobin,    (2E)-2-(methoxyimino)-2-{2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-dien-1-yl]phenyl}-N-methylacetamide    (WO 97/15552);-   picoxystrobin, methyl    3-methoxy-2-[2-(6-trifluoromethylpyridin-2-yloxymethyl)phenyl]-acrylate    (EP-A 278 595);-   pyraclostrobin, methyl    N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate    (WO 96/01256);-   trifloxystrobin, methyl    (E)-methoxyimino-{(E)-α-[1-(α,α,α-trifluoro-m-tolyl)ethylidene-aminooxy]-o-tolyl}acetate    (EP-A 460 575);-   methyl    2-[ortho-(2,5-dimethylphenyloxymethylene)phenyl]-3-methoxyacrylate    (EP-A 226 917);-   5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine    (WO 98/46608);-   3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide (WO    99/24413), compounds of the formula III (WO 04/049804);-   N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide    and    N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide    (WO 03/66609);-   2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103);-   N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide    (WO 03/053145);-   methyl    3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propanoate    (EP-A 1028125).

It is an object of the present invention, with a view to reducing theapplication rates and broadening the activity spectrum of the activecompounds I and II, to provide mixtures which, at a reduced total amountof active compounds applied, have improved activity against harmfulfungi, in particular for certain indications.

We have accordingly found that this object is achieved by the mixtures,defined at the outset, of the active compounds I and II. Moreover, wehave found that simultaneous, that is joint or separate, application ofat least one compound I and at least one of the active compounds II orsuccessive application of the compound(s) I and at least one of theactive compounds II allows better control of harmful fungi than ispossible with the individual compounds alone (synergistic mixtures).

The compounds I can be used as synergists for a large number ofdifferent fungicidal active compounds. By simultaneous, that is joint orseparate, application of compound(s) I with at least one active compoundII, the fungicidal activity is increased in a superadditive manner.

The compounds I can be present in different crystal modifications, whichmay differ in biological activity.

In the formula I, halogen is fluorine, chlorine, bromine or iodine,preferably fluorine or chlorine;

C₁-C₄-alkyl is methyl, ethyl, n-propyl, 1-methylethyl, n-butyl,1-methylpropyl, 2-methylpropyl or 1,1-dimethylethyl, preferably methylor ethyl;

C₁-C₄-haloalkyl is a partially or fully halogenated C₁-C₄-alkyl radical,where the halogen atom(s) is/are in particular fluorine, chlorine and/orbromine, i.e., for example, chloromethyl, bromomethyl, dichloromethyl,trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl,chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl,1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl,2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl,2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl,2,2,2-trichloroethyl, pentafluoroethyl, heptafluoropropyl ornonafluorobutyl, in particular halomethyl, with particular preferenceCH₂—Cl, CH(Cl)₂, CH₂—F, CHF₂, CF₃, CHFCl, CF₂Cl or CF(Cl)₂, inparticular CHF₂ or CF₃;C₁-C₄-alkoxy is OCH₃, OC₂H₅, OCH₂—C₂H₅, OCH(CH₃)₂, n-butoxy,OCH(CH₃)—C₂H₅, OCH₂—CH(CH₃)₂ or OC(CH₃)₃, preferably OCH₃ or OC₂H₅;C₁-C₄-haloalkoxy is a partially or fully halogenated C₁-C₄-alkoxyradical, where the halogen atom(s) is/are in particular fluorine,chlorine and/or bromine, i.e., for example, chloromethoxy, bromomethoxy,dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy,trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy,chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy,2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy,2-chloro-2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy,2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy,heptafluoropropoxy or nonafluorobutoxy, in particular halomethoxy,particularly preferably OCH₂—Cl, OCH(Cl)₂, OCH₂—F, OCH(F)₂, OCF₃,OCHFCl, OCF₂Cl or OCF(Cl)₂;C₁-C₄-alkylthio is SCH₃, SC₂H₅, SCH₂—C₂H₅, SCH(CH₃)₂, n-butylthio,SCH(CH₃)—C₂H₅, SCH₂—CH(CH₃)₂ or SC(CH₃)₃, preferably SCH₃ or SC₂H₅.

Preferred 1-methylpyrazol-4-ylcarboxanilides I are, on the one hand,those in which X is oxygen.

On the other hand, preferred compounds I are those in which X is sulfur.

For the mixtures according to the invention, preference is given tocompounds of the formula I in which R¹ is methyl or halomethyl, inparticular CH₃, CHF₂, CH₂F, CF₃, CHFCl or CF₂Cl.

Preference is furthermore given to compounds I in which R² is hydrogen,fluorine or chlorine, in particular hydrogen.

Preference is furthermore given to those compounds I in which R³ ishalogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy, C₁-C₄-haloalkoxy orC₁-C₄-alkylthio, preferably halogen, methyl, halomethyl, methoxy,halomethoxy or methylthio, in particular F, Cl, CH₃, CF₃, OCH₃, OCHF₂,OCF₃ or SCH₃, particularly preferably fluorine.

Moreover, preference is given to those compounds I in which R⁴ ishalogen, in particular fluorine.

Preference is furthermore given to those compounds I in which R⁵ ishalogen, in particular fluorine.

Particular preference is given to the compounds I listed in Table 1below in which X is oxygen.

TABLE 1 Compound R¹ R² R³ R⁴ R⁵ M.p. [° C.] No. 1 CH₃ H 2-F 3-F 4-F No.2 CH₃ H 2-F 3-F 5-F No. 3 CH₃ H 2-F 4-F 5-F No. 4 CH₃ H 2-F 4-F 6-F No.5 CH₃ H 3-F 4-F 5-F No. 6 CH₃ H 3-F 5-F 6-F No. 7 CH₂F H 2-F 3-F 4-F No.8 CH₂F H 2-F 3-F 5-F No. 9 CH₂F H 2-F 4-F 5-F No. 10 CH₂F H 2-F 4-F 6-FNo. 11 CH₂F H 3-F 4-F 5-F No. 12 CH₂F H 3-F 5-F 6-F No. 13 CHF₂ H 2-F3-F 4-F No. 14 CHF₂ H 2-F 3-F 5-F No. 15 CHF₂ H 2-F 4-F 5-F No. 16 CHF₂H 2-F 4-F 6-F No. 17 CHF₂ H 3-F 4-F 5-F No. 18 CHF₂ H 3-F 5-F 6-F No. 19CF₃ H 2-F 3-F 4-F No. 20 CF₃ H 2-F 3-F 5-F No. 21 CF₃ H 2-F 4-F 5-F No.22 CF₃ H 2-F 4-F 6-F No. 23 CF₃ H 3-F 4-F 5-F No. 24 CF₃ H 3-F 5-F 6-FNo. 25 CHFCl H 2-F 3-F 4-F No. 26 CHFCl H 2-F 3-F 5-F No. 27 CHFCl H 2-F4-F 5-F No. 28 CHFCl H 2-F 4-F 6-F No. 29 CHFCl H 3-F 4-F 5-F No. 30CHFCl H 3-F 5-F 6-F No. 31 CF₂Cl H 2-F 3-F 4-F No. 32 CF₂Cl H 2-F 3-F5-F No. 33 CF₂Cl H 2-F 4-F 5-F No. 34 CF₂Cl H 2-F 4-F 6-F No. 35 CF₂Cl H3-F 4-F 5-F No. 36 CF₂Cl H 3-F 5-F 6-F No. 37 CH₃ F 2-F 3-F 4-F No. 38CH₃ F 2-F 3-F 5-F No. 39 CH₃ F 2-F 4-F 5-F No. 40 CH₃ F 2-F 4-F 6-F No.41 CH₃ F 3-F 4-F 5-F No. 42 CH₃ F 3-F 5-F 6-F No. 43 CH₂F F 2-F 3-F 4-FNo. 44 CH₂F F 2-F 3-F 5-F No. 45 CH₂F F 2-F 4-F 5-F No. 46 CH₂F F 2-F4-F 6-F No. 47 CH₂F F 3-F 4-F 5-F No. 48 CH₂F F 3-F 5-F 6-F No. 49 CHF₂F 2-F 3-F 4-F No. 50 CHF₂ F 2-F 3-F 5-F No. 51 CHF₂ F 2-F 4-F 5-F No. 52CHF₂ F 2-F 4-F 6-F No. 53 CHF₂ F 3-F 4-F 5-F No. 54 CHF₂ F 3-F 5-F 6-FNo. 55 CF₃ F 2-F 3-F 4-F No. 56 CF₃ F 2-F 3-F 5-F No. 57 CF₃ F 2-F 4-F5-F No. 58 CF₃ F 2-F 4-F 6-F No. 59 CF₃ F 3-F 4-F 5-F No. 60 CF₃ F 3-F5-F 6-F No. 61 CHFCl F 2-F 3-F 4-F No. 62 CHFCl F 2-F 3-F 5-F No. 63CHFCl F 2-F 4-F 5-F No. 64 CHFCl F 2-F 4-F 6-F No. 65 CHFCl F 3-F 4-F5-F No. 66 CHFCl F 3-F 5-F 6-F No. 67 CF₂Cl F 2-F 3-F 4-F No. 68 CF₂Cl F2-F 3-F 5-F No. 69 CF₂Cl F 2-F 4-F 5-F No. 70 CF₂Cl F 2-F 4-F 6-F No. 71CF₂Cl F 3-F 4-F 5-F No. 72 CF₂Cl F 3-F 5-F 6-F No. 73 CH₃ Cl 2-F 3-F 4-FNo. 74 CH₃ Cl 2-F 3-F 5-F No. 75 CH₃ Cl 2-F 4-F 5-F No. 76 CH₃ Cl 2-F4-F 6-F No. 77 CH₃ Cl 3-F 4-F 5-F No. 78 CH₃ Cl 3-F 5-F 6-F No. 79 CH₂FCl 2-F 3-F 4-F No. 80 CH₂F Cl 2-F 3-F 5-F No. 81 CH₂F Cl 2-F 4-F 5-F No.82 CH₂F Cl 2-F 4-F 6-F No. 83 CH₂F Cl 3-F 4-F 5-F No. 84 CH₂F Cl 3-F 5-F6-F No. 85 CHF₂ Cl 2-F 3-F 4-F No. 86 CHF₂ Cl 2-F 3-F 5-F No. 87 CHF₂ Cl2-F 4-F 5-F No. 88 CHF₂ Cl 2-F 4-F 6-F No. 89 CHF₂ Cl 3-F 4-F 5-F No. 90CHF₂ Cl 3-F 5-F 6-F No. 91 CF₃ Cl 2-F 3-F 4-F No. 92 CF₃ Cl 2-F 3-F 5-FNo. 93 CF₃ Cl 2-F 4-F 5-F No. 94 CF₃ Cl 2-F 4-F 6-F No. 95 CF₃ Cl 3-F4-F 5-F No. 96 CF₃ Cl 3-F 5-F 6-F No. 97 CHFCl Cl 2-F 3-F 4-F No. 98CHFCl Cl 2-F 3-F 5-F No. 99 CHFCl Cl 2-F 4-F 5-F No. 100 CHFCl Cl 2-F4-F 6-F No. 101 CHFCl Cl 3-F 4-F 5-F No. 102 CHFCl Cl 3-F 5-F 6-F No.103 CF₂Cl Cl 2-F 3-F 4-F No. 104 CF₂Cl Cl 2-F 3-F 5-F No. 105 CF₂Cl Cl2-F 4-F 5-F No. 106 CF₂Cl Cl 2-F 4-F 6-F No. 107 CF₂Cl Cl 3-F 4-F 5-FNo. 108 CF₂Cl Cl 3-F 5-F 6-F

Particular preference is furthermore given to1-methylpyrazol-4-ylcarboxanilides of the formula Ia (I where X=O,R¹=CF₃ and R²=H)

in particular to the compounds Ia.1 to Ia.1009 listed in Table 2 below:

TABLE 2 Compound M.p. No. R¹ R² R³ R⁴ R⁵ [° C.] Ia.1 CF₃ H 2-fluoro3-fluoro 4-fluoro 123-125 Ia.2 CF₃ H 2-fluoro 3-chloro 4-fluoro Ia.3 CF₃H 2-fluoro 3-CN 4-fluoro Ia.4 CF₃ H 2-fluoro 3-methyl 4-fluoro Ia.5 CF₃H 2-fluoro 3-CF₃ 4-fluoro Ia.6 CF₃ H 2-fluoro 3-OCH₃ 4-fluoro Ia.7 CF₃ H2-fluoro 3-OCF₃ 4-fluoro Ia.8 CF₃ H 2-chloro 3-fluoro 4-fluoro Ia.9 CF₃H 2-chloro 3-chloro 4-fluoro Ia.10 CF₃ H 2-chloro 3-CN 4-fluoro Ia.11CF₃ H 2-chloro 3-methyl 4-fluoro Ia.12 CF₃ H 2-chloro 3-CF₃ 4-fluoroIa.13 CF₃ H 2-chloro 3-OCH₃ 4-fluoro Ia.14 CF₃ H 2-chloro 3-OCF₃4-fluoro Ia.15 CF₃ H 2-CN 3-fluoro 4-fluoro Ia.16 CF₃ H 2-CN 3-chloro4-fluoro Ia.17 CF₃ H 2-CN 3-CN 4-fluoro Ia.18 CF₃ H 2-CN 3-methyl4-fluoro Ia.19 CF₃ H 2-CN 3-CF₃ 4-fluoro Ia.20 CF₃ H 2-CN 3-OCH₃4-fluoro Ia.21 CF₃ H 2-CN 3-OCF₃ 4-fluoro Ia.22 CF₃ H 2-methyl 3-fluoro4-fluoro Ia.23 CF₃ H 2-methyl 3-chloro 4-fluoro Ia.24 CF₃ H 2-methyl3-CN 4-fluoro Ia.25 CF₃ H 2-methyl 3-methyl 4-fluoro Ia.26 CF₃ H2-methyl 3-CF₃ 4-fluoro Ia.27 CF₃ H 2-methyl 3-OCH₃ 4-fluoro Ia.28 CF₃ H2-methyl 3-OCF₃ 4-fluoro Ia.29 CF₃ H 2-CF₃ 3-fluoro 4-fluoro Ia.30 CF₃ H2-CF₃ 3-chloro 4-fluoro Ia.31 CF₃ H 2-CF₃ 3-CN 4-fluoro Ia.32 CF₃ H2-CF₃ 3-methyl 4-fluoro Ia.33 CF₃ H 2-CF₃ 3-CF₃ 4-fluoro Ia.34 CF₃ H2-CF₃ 3-OCH₃ 4-fluoro Ia.35 CF₃ H 2-CF₃ 3-OCF₃ 4-fluoro Ia.36 CF₃ H2-OCH₃ 3-fluoro 4-fluoro Ia.37 CF₃ H 2-OCH₃ 3-chloro 4-fluoro Ia.38 CF₃H 2-OCH₃ 3-CN 4-fluoro Ia.39 CF₃ H 2-OCH₃ 3-methyl 4-fluoro Ia.40 CF₃ H2-OCH₃ 3-CF₃ 4-fluoro Ia.41 CF₃ H 2-OCH₃ 3-OCH₃ 4-fluoro Ia.42 CF₃ H2-OCH₃ 3-OCF₃ 4-fluoro Ia.43 CF₃ H 2-OCF₃ 3-fluoro 4-fluoro Ia.44 CF₃ H2-OCF₃ 3-chloro 4-fluoro Ia.45 CF₃ H 2-OCF₃ 3-CN 4-fluoro Ia.46 CF₃ H2-OCF₃ 3-methyl 4-fluoro Ia.47 CF₃ H 2-OCF₃ 3-CF₃ 4-fluoro Ia.48 CF₃ H2-OCF₃ 3-OCH₃ 4-fluoro Ia.49 CF₃ H 2-OCF₃ 3-OCF₃ 4-fluoro Ia.50 CF₃ H2-fluoro 3-fluoro 4-chloro Ia.51 CF₃ H 2-fluoro 3-chloro 4-chloro Ia.52CF₃ H 2-fluoro 3-CN 4-chloro Ia.53 CF₃ H 2-fluoro 3-methyl 4-chloroIa.54 CF₃ H 2-fluoro 3-CF₃ 4-chloro Ia.55 CF₃ H 2-fluoro 3-OCH₃ 4-chloroIa.56 CF₃ H 2-fluoro 3-OCF₃ 4-chloro Ia.57 CF₃ H 2-chloro 3-fluoro4-chloro Ia.58 CF₃ H 2-chloro 3-chloro 4-chloro Ia.59 CF₃ H 2-chloro3-CN 4-chloro Ia.60 CF₃ H 2-chloro 3-methyl 4-chloro Ia.61 CF₃ H2-chloro 3-CF₃ 4-chloro Ia.62 CF₃ H 2-chloro 3-OCH₃ 4-chloro Ia.63 CF₃ H2-chloro 3-OCF₃ 4-chloro Ia.64 CF₃ H 2-CN 3-fluoro 4-chloro Ia.65 CF₃ H2-CN 3-chloro 4-chloro Ia.66 CF₃ H 2-CN 3-CN 4-chloro Ia.67 CF₃ H 2-CN3-methyl 4-chloro Ia.68 CF₃ H 2-CN 3-CF₃ 4-chloro Ia.69 CF₃ H 2-CN3-OCH₃ 4-chloro Ia.70 CF₃ H 2-CN 3-OCF₃ 4-chloro Ia.71 CF₃ H 2-methyl3-fluoro 4-chloro Ia.72 CF₃ H 2-methyl 3-chloro 4-chloro Ia.73 CF₃ H2-methyl 3-CN 4-chloro Ia.74 CF₃ H 2-methyl 3-methyl 4-chloro Ia.75 CF₃H 2-methyl 3-CF₃ 4-chloro Ia.76 CF₃ H 2-methyl 3-OCH₃ 4-chloro Ia.77 CF₃H 2-methyl 3-OCF₃ 4-chloro Ia.78 CF₃ H 2-CF₃ 3-fluoro 4-chloro Ia.79 CF₃H 2-CF₃ 3-chloro 4-chloro Ia.80 CF₃ H 2-CF₃ 3-CN 4-chloro Ia.81 CF₃ H2-CF₃ 3-methyl 4-chloro Ia.82 CF₃ H 2-CF₃ 3-CF₃ 4-chloro Ia.83 CF₃ H2-CF₃ 3-OCH₃ 4-chloro Ia.84 CF₃ H 2-CF₃ 3-OCF₃ 4-chloro Ia.85 CF₃ H2-OCH₃ 3-fluoro 4-chloro Ia.86 CF₃ H 2-OCH₃ 3-chloro 4-chloro Ia.87 CF₃H 2-OCH₃ 3-CN 4-chloro Ia.88 CF₃ H 2-OCH₃ 3-methyl 4-chloro Ia.89 CF₃ H2-OCH₃ 3-CF₃ 4-chloro Ia.90 CF₃ H 2-OCH₃ 3-OCH₃ 4-chloro Ia.91 CF₃ H2-OCH₃ 3-OCF₃ 4-chloro Ia.92 CF₃ H 2-OCF₃ 3-fluoro 4-chloro Ia.93 CF₃ H2-OCF₃ 3-chloro 4-chloro Ia.94 CF₃ H 2-OCF₃ 3-CN 4-chloro Ia.95 CF₃ H2-OCF₃ 3-methyl 4-chloro Ia.96 CF₃ H 2-OCF₃ 3-CF₃ 4-chloro Ia.97 CF₃ H2-OCF₃ 3-OCH₃ 4-chloro Ia.98 CF₃ H 2-OCF₃ 3-OCF₃ 4-chloro Ia.99 CF₃ H2-fluoro 3-fluoro 4-CN Ia.100 CF₃ H 2-fluoro 3-chloro 4-CN Ia.101 CF₃ H2-fluoro 3-CN 4-CN Ia.102 CF₃ H 2-fluoro 3-methyl 4-CN Ia.103 CF₃ H2-fluoro 3-CF₃ 4-CN Ia.104 CF₃ H 2-fluoro 3-OCH₃ 4-CN Ia.105 CF₃ H2-fluoro 3-OCF₃ 4-CN Ia.106 CF₃ H 2-chloro 3-fluoro 4-CN Ia.107 CF₃ H2-chloro 3-chloro 4-CN Ia.108 CF₃ H 2-chloro 3-CN 4-CN Ia.109 CF₃ H2-chloro 3-methyl 4-CN Ia.110 CF₃ H 2-chloro 3-CF₃ 4-CN Ia.111 CF₃ H2-chloro 3-OCH₃ 4-CN Ia.112 CF₃ H 2-chloro 3-OCF₃ 4-CN Ia.113 CF₃ H 2-CN3-fluoro 4-CN Ia.114 CF₃ H 2-CN 3-chloro 4-CN Ia.115 CF₃ H 2-CN 3-CN4-CN Ia.116 CF₃ H 2-CN 3-methyl 4-CN Ia.117 CF₃ H 2-CN 3-CF₃ 4-CN Ia.118CF₃ H 2-CN 3-OCH₃ 4-CN Ia.119 CF₃ H 2-CN 3-OCF₃ 4-CN Ia.120 CF₃ H2-methyl 3-fluoro 4-CN Ia.121 CF₃ H 2-methyl 3-chloro 4-CN Ia.122 CF₃ H2-methyl 3-CN 4-CN Ia.123 CF₃ H 2-methyl 3-methyl 4-CN Ia.124 CF₃ H2-methyl 3-CF₃ 4-CN Ia.125 CF₃ H 2-methyl 3-OCH₃ 4-CN Ia.126 CF₃ H2-methyl 3-OCF₃ 4-CN Ia.127 CF₃ H 2-CF₃ 3-fluoro 4-CN Ia.128 CF₃ H 2-CF₃3-chloro 4-CN Ia.129 CF₃ H 2-CF₃ 3-CN 4-CN Ia.130 CF₃ H 2-CF₃ 3-methyl4-CN Ia.131 CF₃ H 2-CF₃ 3-CF₃ 4-CN Ia.132 CF₃ H 2-CF₃ 3-OCH₃ 4-CN Ia.133CF₃ H 2-CF₃ 3-OCF₃ 4-CN Ia.134 CF₃ H 2-OCH₃ 3-fluoro 4-CN Ia.135 CF₃ H2-OCH₃ 3-chloro 4-CN Ia.136 CF₃ H 2-OCH₃ 3-CN 4-CN Ia.137 CF₃ H 2-OCH₃3-methyl 4-CN Ia.138 CF₃ H 2-OCH₃ 3-CF₃ 4-CN Ia.139 CF₃ H 2-OCH₃ 3-OCH₃4-CN Ia.140 CF₃ H 2-OCH₃ 3-OCF₃ 4-CN Ia.141 CF₃ H 2-OCF₃ 3-fluoro 4-CNIa.142 CF₃ H 2-OCF₃ 3-chloro 4-CN Ia.143 CF₃ H 2-OCF₃ 3-CN 4-CN Ia.144CF₃ H 2-OCF₃ 3-methyl 4-CN Ia.145 CF₃ H 2-OCF₃ 3-CF₃ 4-CN Ia.146 CF₃ H2-OCF₃ 3-OCH₃ 4-CN Ia.147 CF₃ H 2-OCF₃ 3-OCF₃ 4-CN Ia.148 CF₃ H 2-fluoro3-fluoro 4-methyl Ia.149 CF₃ H 2-fluoro 3-chloro 4-methyl Ia.150 CF₃ H2-fluoro 3-CN 4-methyl Ia.151 CF₃ H 2-fluoro 3-methyl 4-methyl Ia.152CF₃ H 2-fluoro 3-CF₃ 4-methyl Ia.153 CF₃ H 2-fluoro 3-OCH₃ 4-methylIa.154 CF₃ H 2-fluoro 3-OCF₃ 4-methyl Ia.155 CF₃ H 2-chloro 3-fluoro4-methyl Ia.156 CF₃ H 2-chloro 3-chloro 4-methyl Ia.157 CF₃ H 2-chloro3-CN 4-methyl Ia.158 CF₃ H 2-chloro 3-methyl 4-methyl Ia.159 CF₃ H2-chloro 3-CF₃ 4-methyl Ia.160 CF₃ H 2-chloro 3-OCH₃ 4-methyl Ia.161 CF₃H 2-chloro 3-OCF₃ 4-methyl Ia.162 CF₃ H 2-CN 3-fluoro 4-methyl Ia.163CF₃ H 2-CN 3-chloro 4-methyl Ia.164 CF₃ H 2-CN 3-CN 4-methyl Ia.165 CF₃H 2-CN 3-methyl 4-methyl Ia.166 CF₃ H 2-CN 3-CF₃ 4-methyl Ia.167 CF₃ H2-CN 3-OCH₃ 4-methyl Ia.168 CF₃ H 2-CN 3-OCF₃ 4-methyl Ia.169 CF₃ H2-methyl 3-fluoro 4-methyl Ia.170 CF₃ H 2-methyl 3-chloro 4-methylIa.171 CF₃ H 2-methyl 3-CN 4-methyl Ia.172 CF₃ H 2-methyl 3-methyl4-methyl Ia.173 CF₃ H 2-methyl 3-CF₃ 4-methyl Ia.174 CF₃ H 2-methyl3-OCH₃ 4-methyl Ia.175 CF₃ H 2-methyl 3-OCF₃ 4-methyl Ia.176 CF₃ H 2-CF₃3-fluoro 4-methyl Ia.177 CF₃ H 2-CF₃ 3-chloro 4-methyl Ia.178 CF₃ H2-CF₃ 3-CN 4-methyl Ia.179 CF₃ H 2-CF₃ 3-methyl 4-methyl Ia.180 CF₃ H2-CF₃ 3-CF₃ 4-methyl Ia.181 CF₃ H 2-CF₃ 3-OCH₃ 4-methyl Ia.182 CF₃ H2-CF₃ 3-OCF₃ 4-methyl Ia.183 CF₃ H 2-OCH₃ 3-fluoro 4-methyl Ia.184 CF₃ H2-OCH₃ 3-chloro 4-methyl Ia.185 CF₃ H 2-OCH₃ 3-CN 4-methyl Ia.186 CF₃ H2-OCH₃ 3-methyl 4-methyl Ia.187 CF₃ H 2-OCH₃ 3-CF₃ 4-methyl Ia.188 CF₃ H2-OCH₃ 3-OCH₃ 4-methyl Ia.189 CF₃ H 2-OCH₃ 3-OCF₃ 4-methyl Ia.190 CF₃ H2-OCF₃ 3-fluoro 4-methyl Ia.191 CF₃ H 2-OCF₃ 3-chloro 4-methyl Ia.192CF₃ H 2-OCF₃ 3-CN 4-methyl Ia.193 CF₃ H 2-OCF₃ 3-methyl 4-methyl Ia.194CF₃ H 2-OCF₃ 3-CF₃ 4-methyl Ia.195 CF₃ H 2-OCF₃ 3-OCH₃ 4-methyl Ia.196CF₃ H 2-OCF₃ 3-OCF₃ 4-methyl Ia.197 CF₃ H 2-fluoro 3-fluoro 4-CF3 Ia.198CF₃ H 2-fluoro 3-chloro 4-CF3 Ia.199 CF₃ H 2-fluoro 3-CN 4-CF3 Ia.200CF₃ H 2-fluoro 3-methyl 4-CF3 Ia.201 CF₃ H 2-fluoro 3-CF₃ 4-CF3 Ia.202CF₃ H 2-fluoro 3-OCH₃ 4-CF3 Ia.203 CF₃ H 2-fluoro 3-OCF₃ 4-CF3 Ia.204CF₃ H 2-chloro 3-fluoro 4-CF₃ Ia.205 CF₃ H 2-chloro 3-chloro 4-CF₃Ia.206 CF₃ H 2-chloro 3-CN 4-CF₃ Ia.207 CF₃ H 2-chloro 3-methyl 4-CF₃Ia.208 CF₃ H 2-chloro 3-CF₃ 4-CF₃ Ia.209 CF₃ H 2-chloro 3-OCH₃ 4-CF₃Ia.210 CF₃ H 2-chloro 3-OCF₃ 4-CF₃ Ia.211 CF₃ H 2-CN 3-fluoro 4-CF₃Ia.212 CF₃ H 2-CN 3-chloro 4-CF₃ Ia.213 CF₃ H 2-CN 3-CN 4-CF₃ Ia.214 CF₃H 2-CN 3-methyl 4-CF₃ Ia.215 CF₃ H 2-CN 3-CF₃ 4-CF₃ Ia.216 CF₃ H 2-CN3-OCH₃ 4-CF₃ Ia.217 CF₃ H 2-CN 3-OCF₃ 4-CF₃ Ia.218 CF₃ H 2-methyl3-fluoro 4-CF3 Ia.219 CF₃ H 2-methyl 3-chloro 4-CF3 Ia.220 CF₃ H2-methyl 3-CN 4-CF3 Ia.221 CF₃ H 2-methyl 3-methyl 4-CF3 Ia.222 CF₃ H2-methyl 3-CF₃ 4-CF3 Ia.223 CF₃ H 2-methyl 3-OCH₃ 4-CF3 Ia.224 CF₃ H2-methyl 3-OCF₃ 4-CF3 Ia.225 CF₃ H 2-CF₃ 3-fluoro 4-CF3 Ia.226 CF₃ H2-CF₃ 3-chloro 4-CF₃ Ia.227 CF₃ H 2-CF₃ 3-CN 4-CF3 Ia.228 CF₃ H 2-CF₃3-methyl 4-CF3 Ia.229 CF₃ H 2-CF₃ 3-CF₃ 4-CF3 Ia.230 CF₃ H 2-CF₃ 3-OCH₃4-CF3 Ia.231 CF₃ H 2-CF₃ 3-OCF₃ 4-CF3 Ia.232 CF₃ H 2-OCH₃ 3-fluoro 4-CF3Ia.233 CF₃ H 2-OCH₃ 3-chloro 4-CF3 Ia.234 CF₃ H 2-OCH₃ 3-CN 4-CF3 Ia.235CF₃ H 2-OCH₃ 3-methyl 4-CF3 Ia.236 CF₃ H 2-OCH₃ 3-CF₃ 4-CF3 Ia.237 CF₃ H2-OCH₃ 3-OCH₃ 4-CF₃ Ia.238 CF₃ H 2-OCH₃ 3-OCF₃ 4-CF₃ Ia.239 CF₃ H 2-OCF₃3-fluoro 4-CF₃ Ia.240 CF₃ H 2-OCF₃ 3-chloro 4-CF₃ Ia.241 CF₃ H 2-OCF₃3-CN 4-CF₃ Ia.242 CF₃ H 2-OCF₃ 3-methyl 4-CF₃ Ia.243 CF₃ H 2-OCF₃ 3-CF₃4-CF₃ Ia.244 CF₃ H 2-OCF₃ 3-OCH₃ 4-CF₃ Ia.245 CF₃ H 2-OCF₃ 3-OCF₃ 4-CF₃Ia.246 CF₃ H 2-fluoro 3-fluoro 4-OCH₃ Ia.247 CF₃ H 2-fluoro 3-chloro4-OCH₃ Ia.248 CF₃ H 2-fluoro 3-CN 4-OCH₃ Ia.249 CF₃ H 2-fluoro 3-methyl4-OCH₃ Ia.250 CF₃ H 2-fluoro 3-CF₃ 4-OCH₃ Ia.251 CF₃ H 2-fluoro 3-OCH₃4-OCH₃ Ia.252 CF₃ H 2-fluoro 3-OCF₃ 4-OCH₃ Ia.253 CF₃ H 2-chloro3-fluoro 4-OCH₃ Ia.254 CF₃ H 2-chloro 3-chloro 4-OCH₃ Ia.255 CF₃ H2-chloro 3-CN 4-OCH₃ Ia.256 CF₃ H 2-chloro 3-methyl 4-OCH₃ Ia.257 CF₃ H2-chloro 3-CF₃ 4-OCH₃ Ia.258 CF₃ H 2-chloro 3-OCH₃ 4-OCH₃ Ia.259 CF₃ H2-chloro 3-OCF₃ 4-OCH₃ Ia.260 CF₃ H 2-CN 3-fluoro 4-OCH₃ Ia.261 CF₃ H2-CN 3-chloro 4-OCH₃ Ia.262 CF₃ H 2-CN 3-CN 4-OCH₃ Ia.263 CF₃ H 2-CN3-methyl 4-OCH₃ Ia.264 CF₃ H 2-CN 3-CF₃ 4-OCH₃ Ia.265 CF₃ H 2-CN 3-OCH₃4-OCH₃ Ia.266 CF₃ H 2-CN 3-OCF₃ 4-OCH₃ Ia.267 CF₃ H 2-methyl 3-fluoro4-OCH₃ Ia.268 CF₃ H 2-methyl 3-chloro 4-OCH₃ Ia.269 CF₃ H 2-methyl 3-CN4-OCH₃ Ia.270 CF₃ H 2-methyl 3-methyl 4-OCH₃ Ia.271 CF₃ H 2-methyl 3-CF₃4-OCH₃ Ia.272 CF₃ H 2-methyl 3-OCH₃ 4-OCH₃ Ia.273 CF₃ H 2-methyl 3-OCF₃4-OCH₃ Ia.274 CF₃ H 2-CF₃ 3-fluoro 4-OCH₃ Ia.275 CF₃ H 2-CF₃ 3-chloro4-OCH₃ Ia.276 CF₃ H 2-CF₃ 3-CN 4-OCH₃ Ia.277 CF₃ H 2-CF₃ 3-methyl 4-OCH₃Ia.278 CF₃ H 2-CF₃ 3-CF₃ 4-OCH₃ Ia.279 CF₃ H 2-CF₃ 3-OCH₃ 4-OCH₃ Ia.280CF₃ H 2-CF₃ 3-OCF₃ 4-OCH₃ Ia.281 CF₃ H 2-OCH₃ 3-fluoro 4-OCH₃ Ia.282 CF₃H 2-OCH₃ 3-chloro 4-OCH₃ Ia.283 CF₃ H 2-OCH₃ 3-CN 4-OCH₃ Ia.284 CF₃ H2-OCH₃ 3-methyl 4-OCH₃ Ia.285 CF₃ H 2-OCH₃ 3-CF₃ 4-OCH₃ Ia.286 CF₃ H2-OCH₃ 3-OCH₃ 4-OCH₃ Ia.287 CF₃ H 2-OCH₃ 3-OCF₃ 4-OCH₃ Ia.288 CF₃ H2-OCF₃ 3-fluoro 4-OCH₃ Ia.289 CF₃ H 2-OCF₃ 3-chloro 4-OCH₃ Ia.290 CF₃ H2-OCF₃ 3-CN 4-OCH₃ Ia.291 CF₃ H 2-OCF₃ 3-methyl 4-OCH₃ Ia.292 CF₃ H2-OCF₃ 3-CF₃ 4-OCH₃ Ia.293 CF₃ H 2-OCF₃ 3-OCH₃ 4-OCH₃ Ia.294 CF₃ H2-OCF₃ 3-OCF₃ 4-OCH₃ Ia.295 CF₃ H 2-fluoro 3-fluoro 4-OCF₃ Ia.296 CF₃ H2-fluoro 3-chloro 4-OCF₃ Ia.297 CF₃ H 2-fluoro 3-CN 4-OCF₃ Ia.298 CF₃ H2-fluoro 3-methyl 4-OCF₃ Ia.299 CF₃ H 2-fluoro 3-CF₃ 4-OCF₃ Ia.300 CF₃ H2-fluoro 3-OCH₃ 4-OCF₃ Ia.301 CF₃ H 2-fluoro 3-OCF₃ 4-OCF₃ Ia.302 CF₃ H2-chloro 3-fluoro 4-OCF₃ Ia.303 CF₃ H 2-chloro 3-chloro 4-OCF₃ Ia.304CF₃ H 2-chloro 3-CN 4-OCF₃ Ia.305 CF₃ H 2-chloro 3-methyl 4-OCF₃ Ia.306CF₃ H 2-chloro 3-CF₃ 4-OCF₃ Ia.307 CF₃ H 2-chloro 3-OCH₃ 4-OCF₃ Ia.308CF₃ H 2-chloro 3-OCF₃ 4-OCF₃ Ia.309 CF₃ H 2-CN 3-fluoro 4-OCF₃ Ia.310CF₃ H 2-CN 3-chloro 4-OCF₃ Ia.311 CF₃ H 2-CN 3-CN 4-OCF₃ Ia.312 CF₃ H2-CN 3-methyl 4-OCF₃ Ia.313 CF₃ H 2-CN 3-CF₃ 4-OCF₃ Ia.314 CF₃ H 2-CN3-OCH₃ 4-OCF₃ Ia.315 CF₃ H 2-CN 3-OCF₃ 4-OCF₃ Ia.316 CF₃ H 2-methyl3-fluoro 4-OCF₃ Ia.317 CF₃ H 2-methyl 3-chloro 4-OCF₃ Ia.318 CF₃ H2-methyl 3-CN 4-OCF₃ Ia.319 CF₃ H 2-methyl 3-methyl 4-OCF₃ Ia.320 CF₃ H2-methyl 3-CF₃ 4-OCF₃ Ia.321 CF₃ H 2-methyl 3-OCH₃ 4-OCF₃ Ia.322 CF₃ H2-methyl 3-OCF₃ 4-OCF₃ Ia.323 CF₃ H 2-CF₃ 3-fluoro 4-OCF₃ Ia.324 CF₃ H2-CF₃ 3-chloro 4-OCF₃ Ia.325 CF₃ H 2-CF₃ 3-CN 4-OCF₃ Ia.326 CF₃ H 2-CF₃3-methyl 4-OCF₃ Ia.327 CF₃ H 2-CF₃ 3-CF₃ 4-OCF₃ Ia.328 CF₃ H 2-CF₃3-OCH₃ 4-OCF₃ Ia.329 CF₃ H 2-CF₃ 3-OCF₃ 4-OCF₃ Ia.330 CF₃ H 2-OCH₃3-fluoro 4-OCF₃ Ia.331 CF₃ H 2-OCH₃ 3-chloro 4-OCF₃ Ia.332 CF₃ H 2-OCH₃3-CN 4-OCF₃ Ia.333 CF₃ H 2-OCH₃ 3-methyl 4-OCF₃ Ia.334 CF₃ H 2-OCH₃3-CF₃ 4-OCF₃ Ia.335 CF₃ H 2-OCH₃ 3-OCH₃ 4-OCF₃ Ia.336 CF₃ H 2-OCH₃3-OCF₃ 4-OCF₃ Ia.337 CF₃ H 2-OCF₃ 3-fluoro 4-OCF₃ Ia.338 CF₃ H 2-OCF₃3-chloro 4-OCF₃ Ia.339 CF₃ H 2-OCF₃ 3-CN 4-OCF₃ Ia.340 CF₃ H 2-OCF₃3-methyl 4-OCF₃ Ia.341 CF₃ H 2-OCF₃ 3-CF₃ 4-OCF₃ Ia.342 CF₃ H 2-OCF₃3-OCH₃ 4-OCF₃ Ia.343 CF₃ H 2-OCF₃ 3-OCF₃ 4-OCF₃ Ia.344 CF₃ H 3-fluoro4-fluoro 5-fluoro 120-124 Ia.345 CF₃ H 3-chloro 4-fluoro 5-fluoro Ia.346CF₃ H 3-CN 4-fluoro 5-fluoro Ia.347 CF₃ H 3-CH₃ 4-fluoro 5-fluoro Ia.348CF₃ H 3-CF₃ 4-fluoro 5-fluoro Ia.349 CF₃ H 3-OCH₃ 4-fluoro 5-fluoroIa.350 CF₃ H 3-OCF₃ 4-fluoro 5-fluoro Ia.351 CF₃ H 3-fluoro 4-fluoro5-chloro Ia.352 CF₃ H 3-chloro 4-fluoro 5-chloro Ia.353 CF₃ H 3-CN4-fluoro 5-chloro Ia.354 CF₃ H 3-CH₃ 4-fluoro 5-chloro Ia.355 CF₃ H3-CF₃ 4-fluoro 5-chloro Ia.356 CF₃ H 3-OCH₃ 4-fluoro 5-chloro Ia.357 CF₃H 3-OCF₃ 4-fluoro 5-chloro Ia.358 CF₃ H 3-fluoro 4-fluoro 5-CN Ia.359CF₃ H 3-chloro 4-fluoro 5-CN Ia.360 CF₃ H 3-CN 4-fluoro 5-CN Ia.361 CF₃H 3-CH₃ 4-fluoro 5-CN Ia.362 CF₃ H 3-CF₃ 4-fluoro 5-CN Ia.363 CF₃ H3-OCH₃ 4-fluoro 5-CN Ia.364 CF₃ H 3-OCF₃ 4-fluoro 5-CN Ia.365 CF₃ H3-fluoro 4-fluoro 5-CH₃ Ia.366 CF₃ H 3-chloro 4-fluoro 5-CH₃ Ia.367 CF₃H 3-CN 4-fluoro 5-CH₃ Ia.368 CF₃ H 3-CH₃ 4-fluoro 5-CH₃ Ia.369 CF₃ H3-CF₃ 4-fluoro 5-CH₃ Ia.370 CF₃ H 3-OCH₃ 4-fluoro 5-CH₃ Ia.371 CF₃ H3-OCF₃ 4-fluoro 5-CH₃ Ia.372 CF₃ H 3-fluoro 4-fluoro 5-CF₃ Ia.373 CF₃ H3-chloro 4-fluoro 5-CF₃ Ia.374 CF₃ H 3-CN 4-fluoro 5-CF₃ Ia.375 CF₃ H3-CH₃ 4-fluoro 5-CF₃ Ia.376 CF₃ H 3-CF₃ 4-fluoro 5-CF₃ Ia.377 CF₃ H3-OCH₃ 4-fluoro 5-CF₃ Ia.378 CF₃ H 3-OCF₃ 4-fluoro 5-CF₃ Ia.379 CF₃ H3-fluoro 4-fluoro 5-OCH₃ Ia.380 CF₃ H 3-chloro 4-fluoro 5-OCH₃ Ia.381CF₃ H 3-CN 4-fluoro 5-OCH₃ Ia.382 CF₃ H 3-CH₃ 4-fluoro 5-OCH₃ Ia.383 CF₃H 3-CF₃ 4-fluoro 5-OCH₃ Ia.384 CF₃ H 3-OCH₃ 4-fluoro 5-OCH₃ Ia.385 CF₃ H3-OCF₃ 4-fluoro 5-OCH₃ Ia.386 CF₃ H 3-fluoro 4-fluoro 5-OCF₃ Ia.387 CF₃H 3-chloro 4-fluoro 5-OCF₃ Ia.388 CF₃ H 3-CN 4-fluoro 5-OCF₃ Ia.389 CF₃H 3-CH₃ 4-fluoro 5-OCF₃ Ia.390 CF₃ H 3-CF₃ 4-fluoro 5-OCF₃ Ia.391 CF₃ H3-OCH₃ 4-fluoro 5-OCF₃ Ia.392 CF₃ H 3-OCF₃ 4-fluoro 5-OCF₃ Ia.393 CF₃ H3-fluoro 4-chloro 5-fluoro Ia.394 CF₃ H 3-chloro 4-chloro 5-fluoroIa.395 CF₃ H 3-CN 4-chloro 5-fluoro Ia.396 CF₃ H 3-CH₃ 4-chloro 5-fluoroIa.397 CF₃ H 3-CF₃ 4-chloro 5-fluoro Ia.398 CF₃ H 3-OCH₃ 4-chloro5-fluoro Ia.399 CF₃ H 3-OCF₃ 4-chloro 5-fluoro Ia.400 CF₃ H 3-fluoro4-chloro 5-chloro Ia.401 CF₃ H 3-chloro 4-chloro 5-chloro Ia.402 CF₃ H3-CN 4-chloro 5-chloro Ia.403 CF₃ H 3-CH₃ 4-chloro 5-chloro Ia.404 CF₃ H3-CF₃ 4-chloro 5-chloro Ia.405 CF₃ H 3-OCH₃ 4-chloro 5-chloro Ia.406 CF₃H 3-OCF₃ 4-chloro 5-chloro Ia.407 CF₃ H 3-fluoro 4-chloro 5-CN Ia.408CF₃ H 3-chloro 4-chloro 5-CN Ia.409 CF₃ H 3-CN 4-chloro 5-CN Ia.410 CF₃H 3-CH₃ 4-chloro 5-CN Ia.411 CF₃ H 3-CF₃ 4-chloro 5-CN Ia.412 CF₃ H3-OCH₃ 4-chloro 5-CN Ia.413 CF₃ H 3-OCF₃ 4-chloro 5-CN Ia.414 CF₃ H3-fluoro 4-chloro 5-CH₃ Ia.415 CF₃ H 3-chloro 4-chloro 5-CH₃ Ia.416 CF₃H 3-CN 4-chloro 5-CH₃ Ia.417 CF₃ H 3-CH₃ 4-chloro 5-CH₃ Ia.418 CF₃ H3-CF₃ 4-chloro 5-CH₃ Ia.419 CF₃ H 3-OCH₃ 4-chloro 5-CH₃ Ia.420 CF₃ H3-OCF₃ 4-chloro 5-CH₃ Ia.421 CF₃ H 3-fluoro 4-chloro 5-CF₃ Ia.422 CF₃ H3-chloro 4-chloro 5-CF₃ Ia.423 CF₃ H 3-CN 4-chloro 5-CF₃ Ia.424 CF₃ H3-CH₃ 4-chloro 5-CF₃ Ia.425 CF₃ H 3-CF₃ 4-chloro 5-CF₃ Ia.426 CF₃ H3-OCH₃ 4-chloro 5-CF₃ Ia.427 CF₃ H 3-OCF₃ 4-chloro 5-CF₃ Ia.428 CF₃ H3-fluoro 4-chloro 5-OCH₃ Ia.429 CF₃ H 3-chloro 4-chloro 5-OCH₃ Ia.430CF₃ H 3-CN 4-chloro 5-OCH₃ Ia.431 CF₃ H 3-CH₃ 4-chloro 5-OCH₃ Ia.432 CF₃H 3-CF₃ 4-chloro 5-OCH₃ Ia.433 CF₃ H 3-OCH₃ 4-chloro 5-OCH₃ Ia.434 CF₃ H3-OCF₃ 4-chloro 5-OCH₃ Ia.435 CF₃ H 3-fluoro 4-chloro 5-OCF₃ Ia.436 CF₃H 3-chloro 4-chloro 5-OCF₃ Ia.437 CF₃ H 3-CN 4-chloro 5-OCF₃ Ia.438 CF₃H 3-CH₃ 4-chloro 5-OCF₃ Ia.439 CF₃ H 3-CF₃ 4-chloro 5-OCF₃ Ia.440 CF₃ H3-OCH₃ 4-chloro 5-OCF₃ Ia.441 CF₃ H 3-OCF₃ 4-chloro 5-OCF₃ Ia.442 CF₃ H3-fluoro 4-CN 5-fluoro Ia.443 CF₃ H 3-chloro 4-CN 5-fluoro Ia.444 CF₃ H3-CN 4-CN 5-fluoro Ia.445 CF₃ H 3-CH₃ 4-CN 5-fluoro Ia.446 CF₃ H 3-CF₃4-CN 5-fluoro Ia.447 CF₃ H 3-OCH₃ 4-CN 5-fluoro Ia.448 CF₃ H 3-OCF₃ 4-CN5-fluoro Ia.449 CF₃ H 3-fluoro 4-CN 5-chloro Ia.450 CF₃ H 3-chloro 4-CN5-chloro Ia.451 CF₃ H 3-CN 4-CN 5-chloro Ia.452 CF₃ H 3-CH₃ 4-CN5-chloro Ia.453 CF₃ H 3-CF₃ 4-CN 5-chloro Ia.454 CF₃ H 3-OCH₃ 4-CN5-chloro Ia.455 CF₃ H 3-OCF₃ 4-CN 5-chloro Ia.456 CF₃ H 3-fluoro 4-CN5-CN Ia.457 CF₃ H 3-chloro 4-CN 5-CN Ia.458 CF₃ H 3-CN 4-CN 5-CN Ia.459CF₃ H 3-CH₃ 4-CN 5-CN Ia.460 CF₃ H 3-CF₃ 4-CN 5-CN Ia.461 CF₃ H 3-OCH₃4-CN 5-CN Ia.462 CF₃ H 3-OCF₃ 4-CN 5-CN Ia.463 CF₃ H 3-fluoro 4-CN 5-CH₃Ia.464 CF₃ H 3-chloro 4-CN 5-CH₃ Ia.465 CF₃ H 3-CN 4-CN 5-CH₃ Ia.466 CF₃H 3-CH₃ 4-CN 5-CH₃ Ia.467 CF₃ H 3-CF₃ 4-CN 5-CH₃ Ia.468 CF₃ H 3-OCH₃4-CN 5-CH₃ Ia.469 CF₃ H 3-OCF₃ 4-CN 5-CH₃ Ia.470 CF₃ H 3-fluoro 4-CN5-CF₃ Ia.471 CF₃ H 3-chloro 4-CN 5-CF₃ Ia.472 CF₃ H 3-CN 4-CN 5-CF₃Ia.473 CF₃ H 3-CH₃ 4-CN 5-CF₃ Ia.474 CF₃ H 3-CF₃ 4-CN 5-CF₃ Ia.475 CF₃ H3-OCH₃ 4-CN 5-CF₃ Ia.476 CF₃ H 3-OCF₃ 4-CN 5-CF₃ Ia.477 CF₃ H 3-fluoro4-CN 5-OCH₃ Ia.478 CF₃ H 3-chloro 4-CN 5-OCH₃ Ia.479 CF₃ H 3-CN 4-CN5-OCH₃ Ia.480 CF₃ H 3-CH₃ 4-CN 5-OCH₃ Ia.481 CF₃ H 3-CF₃ 4-CN 5-OCH₃Ia.482 CF₃ H 3-OCH₃ 4-CN 5-OCH₃ Ia.483 CF₃ H 3-OCF₃ 4-CN 5-OCH₃ Ia.484CF₃ H 3-fluoro 4-CN 5-OCF₃ Ia.485 CF₃ H 3-chloro 4-CN 5-OCF₃ Ia.486 CF₃H 3-CN 4-CN 5-OCF₃ Ia.487 CF₃ H 3-CH₃ 4-CN 5-OCF₃ Ia.488 CF₃ H 3-CF₃4-CN 5-OCF₃ Ia.489 CF₃ H 3-OCH₃ 4-CN 5-OCF₃ Ia.490 CF₃ H 3-OCF₃ 4-CN5-OCF₃ Ia.491 CF₃ H 3-fluoro 4-CH₃ 5-fluoro Ia.492 CF₃ H 3-chloro 4-CH₃5-fluoro Ia.493 CF₃ H 3-CN 4-CH₃ 5-fluoro Ia.494 CF₃ H 3-CH₃ 4-CH₃5-fluoro Ia.495 CF₃ H 3-CF₃ 4-CH₃ 5-fluoro Ia.496 CF₃ H 3-OCH₃ 4-CH₃5-fluoro Ia.497 CF₃ H 3-OCF₃ 4-CH₃ 5-fluoro Ia.498 CF₃ H 3-fluoro 4-CH₃5-chloro Ia.499 CF₃ H 3-chloro 4-CH₃ 5-chloro Ia.500 CF₃ H 3-CN 4-CH₃5-chloro Ia.501 CF₃ H 3-CH₃ 4-CH₃ 5-chloro Ia.502 CF₃ H 3-CF₃ 4-CH₃5-chloro Ia.503 CF₃ H 3-OCH₃ 4-CH₃ 5-chloro Ia.504 CF₃ H 3-OCF₃ 4-CH₃5-chloro Ia.505 CF₃ H 3-fluoro 4-CH₃ 5-CN Ia.506 CF₃ H 3-chloro 4-CH₃5-CN Ia.507 CF₃ H 3-CN 4-CH₃ 5-CN Ia.508 CF₃ H 3-CH₃ 4-CH₃ 5-CN Ia.509CF₃ H 3-CF₃ 4-CH₃ 5-CN Ia.510 CF₃ H 3-OCH₃ 4-CH₃ 5-CN Ia.511 CF₃ H3-OCF₃ 4-CH₃ 5-CN Ia.512 CF₃ H 3-fluoro 4-CH₃ 5-CH₃ Ia.513 CF₃ H3-chloro 4-CH₃ 5-CH₃ Ia.514 CF₃ H 3-CN 4-CH₃ 5-CH₃ Ia.515 CF₃ H 3-CH₃4-CH₃ 5-CH₃ Ia.516 CF₃ H 3-CF₃ 4-CH₃ 5-CH₃ Ia.517 CF₃ H 3-OCH₃ 4-CH₃5-CH₃ Ia.518 CF₃ H 3-OCF₃ 4-CH₃ 5-CH₃ Ia.519 CF₃ H 3-fluoro 4-CH₃ 5-CF₃Ia.520 CF₃ H 3-chloro 4-CH₃ 5-CF₃ Ia.521 CF₃ H 3-CN 4-CH₃ 5-CF₃ Ia.522CF₃ H 3-CH₃ 4-CH₃ 5-CF₃ Ia.523 CF₃ H 3-CF₃ 4-CH₃ 5-CF₃ Ia.524 CF₃ H3-OCH₃ 4-CH₃ 5-CF₃ Ia.525 CF₃ H 3-OCF₃ 4-CH₃ 5-CF₃ Ia.526 CF₃ H 3-fluoro4-CH₃ 5-OCH₃ Ia.527 CF₃ H 3-chloro 4-CH₃ 5-OCH₃ Ia.528 CF₃ H 3-CN 4-CH₃5-OCH₃ Ia.529 CF₃ H 3-CH₃ 4-CH₃ 5-OCH₃ Ia.530 CF₃ H 3-CF₃ 4-CH₃ 5-OCH₃Ia.531 CF₃ H 3-OCH₃ 4-CH₃ 5-OCH₃ Ia.532 CF₃ H 3-OCF₃ 4-CH₃ 5-OCH₃ Ia.533CF₃ H 3-fluoro 4-CH₃ 5-OCF₃ Ia.534 CF₃ H 3-chloro 4-CH₃ 5-OCF₃ Ia.535CF₃ H 3-CN 4-CH₃ 5-OCF₃ Ia.536 CF₃ H 3-CH₃ 4-CH₃ 5-OCF₃ Ia.537 CF₃ H3-CF₃ 4-CH₃ 5-OCF₃ Ia.538 CF₃ H 3-OCH₃ 4-CH₃ 5-OCF₃ Ia.539 CF₃ H 3-OCF₃4-CH₃ 5-OCF₃ Ia.540 CF₃ H 3-fluoro 4-CF₃ 5-fluoro Ia.541 CF₃ H 3-chloro4-CF₃ 5-fluoro Ia.542 CF₃ H 3-CN 4-CF₃ 5-fluoro Ia.543 CF₃ H 3-CH₃ 4-CF₃5-fluoro Ia.544 CF₃ H 3-CF₃ 4-CF₃ 5-fluoro Ia.545 CF₃ H 3-OCH₃ 4-CF₃5-fluoro Ia.546 CF₃ H 3-OCF₃ 4-CF₃ 5-fluoro Ia.547 CF₃ H 3-fluoro 4-CF₃5-chloro Ia.548 CF₃ H 3-chloro 4-CF₃ 5-chloro Ia.549 CF₃ H 3-CN 4-CF₃5-chloro Ia.550 CF₃ H 3-CH₃ 4-CF₃ 5-chloro Ia.551 CF₃ H 3-CF₃ 4-CF₃5-chloro Ia.552 CF₃ H 3-OCH₃ 4-CF₃ 5-chloro Ia.553 CF₃ H 3-OCF₃ 4-CF₃5-chloro Ia.554 CF₃ H 3-fluoro 4-CF₃ 5-CN Ia.555 CF₃ H 3-chloro 4-CF₃5-CN Ia.556 CF₃ H 3-CN 4-CF₃ 5-CN Ia.557 CF₃ H 3-CH₃ 4-CF₃ 5-CN Ia.558CF₃ H 3-CF₃ 4-CF₃ 5-CN Ia.559 CF₃ H 3-OCH₃ 4-CF₃ 5-CN Ia.560 CF₃ H3-OCF₃ 4-CF₃ 5-CN Ia.561 CF₃ H 3-fluoro 4-CF₃ 5-CH₃ Ia.562 CF₃ H3-chloro 4-CF₃ 5-CH₃ Ia.563 CF₃ H 3-CN 4-CF₃ 5-CH₃ Ia.564 CF₃ H 3-CH₃4-CF₃ 5-CH₃ Ia.565 CF₃ H 3-CF₃ 4-CF₃ 5-CH₃ Ia.566 CF₃ H 3-OCH₃ 4-CF₃5-CH₃ Ia.567 CF₃ H 3-OCF₃ 4-CF₃ 5-CH₃ Ia.568 CF₃ H 3-fluoro 4-CF₃ 5-OCF₃Ia.569 CF₃ H 3-chloro 4-CF₃ 5-CF₃ Ia.570 CF₃ H 3-CN 4-CF₃ 5-CF₃ Ia.571CF₃ H 3-CH₃ 4-CF₃ 5-CF₃ Ia.572 CF₃ H 3-CF₃ 4-CF₃ 5-CF₃ Ia.573 CF₃ H3-OCH₃ 4-CF₃ 5-CF₃ Ia.574 CF₃ H 3-OCF₃ 4-CF₃ 5-CF₃ Ia.575 CF₃ H 3-fluoro4-CF₃ 5-OCH₃ Ia.576 CF₃ H 3-chloro 4-CF₃ 5-OCH₃ Ia.577 CF₃ H 3-CN 4-CF₃5-OCH₃ Ia.578 CF₃ H 3-CH₃ 4-CF₃ 5-OCH₃ Ia.579 CF₃ H 3-CF₃ 4-CF₃ 5-OCH₃Ia.560 CF₃ H 3-OCH₃ 4-CF₃ 5-OCH₃ Ia.561 CF₃ H 3-OCF₃ 4-CF₃ 5-OCH₃ Ia.562CF₃ H 3-fluoro 4-CF₃ 5-OCF₃ Ia.563 CF₃ H 3-chloro 4-CF₃ 5-OCF₃ Ia.564CF₃ H 3-CN 4-CF₃ 5-OCF₃ Ia.565 CF₃ H 3-CH₃ 4-CF₃ 5-OCF₃ Ia.566 CF₃ H3-CF₃ 4-CF₃ 5-OCF₃ Ia.567 CF₃ H 3-OCH₃ 4-CF₃ 5-OCF₃ Ia.568 CF₃ H 3-OCF₃4-CF₃ 5-OCF₃ Ia.569 CF₃ H 3-fluoro 4-OCH₃ 5-fluoro Ia.570 CF₃ H 3-chloro4-OCH₃ 5-fluoro Ia.571 CF₃ H 3-CN 4-OCH₃ 5-fluoro Ia.572 CF₃ H 3-CH₃4-OCH₃ 5-fluoro Ia.573 CF₃ H 3-CF₃ 4-OCH₃ 5-fluoro Ia.574 CF₃ H 3-OCH₃4-OCH₃ 5-fluoro Ia.575 CF₃ H 3-OCF₃ 4-OCH₃ 5-fluoro Ia.576 CF₃ H3-fluoro 4-OCH₃ 5-chloro Ia.577 CF₃ H 3-chloro 4-OCH₃ 5-chloro Ia.578CF₃ H 3-CN 4-OCH₃ 5-chloro Ia.579 CF₃ H 3-CH₃ 4-OCH₃ 5-chloro Ia.580 CF₃H 3-CF₃ 4-OCH₃ 5-chloro Ia.581 CF₃ H 3-OCH₃ 4-OCH₃ 5-chloro Ia.582 CF₃ H3-OCF₃ 4-OCH₃ 5-chloro Ia.583 CF₃ H 3-fluoro 4-OCH₃ 5-CN Ia.584 CF₃ H3-chloro 4-OCH₃ 5-CN Ia.585 CF₃ H 3-CN 4-OCH₃ 5-CN Ia.586 CF₃ H 3-CH₃4-OCH₃ 5-CN Ia.587 CF₃ H 3-CF₃ 4-OCH₃ 5-CN Ia.588 CF₃ H 3-OCH₃ 4-OCH₃5-CN Ia.589 CF₃ H 3-OCF₃ 4-OCH₃ 5-CN Ia.590 CF₃ H 3-fluoro 4-OCH₃ 5-CH₃Ia.591 CF₃ H 3-chloro 4-OCH₃ 5-CH₃ Ia.592 CF₃ H 3-CN 4-OCH₃ 5-CH₃ Ia.593CF₃ H 3-CH₃ 4-OCH₃ 5-CH₃ Ia.594 CF₃ H 3-CF₃ 4-OCH₃ 5-CH₃ Ia.595 CF₃ H3-OCH₃ 4-OCH₃ 5-CH₃ Ia.596 CF₃ H 3-OCF₃ 4-OCH₃ 5-CH₃ Ia.597 CF₃ H3-fluoro 4-OCH₃ 5-CF₃ Ia.598 CF₃ H 3-chloro 4-OCH₃ 5-CF₃ Ia.599 CF₃ H3-CN 4-OCH₃ 5-CF₃ Ia.600 CF₃ H 3-CH₃ 4-OCH₃ 5-CF₃ Ia.601 CF₃ H 3-CF₃4-OCH₃ 5-CF₃ Ia.602 CF₃ H 3-OCH₃ 4-OCH₃ 5-CF₃ Ia.603 CF₃ H 3-OCF₃ 4-OCH₃5-CF₃ Ia.604 CF₃ H 3-fluoro 4-OCH₃ 5-OCH₃ Ia.605 CF₃ H 3-chloro 4-OCH₃5-OCH₃ Ia.606 CF₃ H 3-CN 4-OCH₃ 5-OCH₃ Ia.607 CF₃ H 3-CH₃ 4-OCH₃ 5-OCH₃Ia.608 CF₃ H 3-CF₃ 4-OCH₃ 5-OCH₃ Ia.609 CF₃ H 3-OCH₃ 4-OCH₃ 5-OCH₃Ia.610 CF₃ H 3-OCF₃ 4-OCH₃ 5-OCH₃ Ia.611 CF₃ H 3-fluoro 4-OCH₃ 5-OCF₃Ia.612 CF₃ H 3-chloro 4-OCH₃ 5-OCF₃ Ia.613 CF₃ H 3-CN 4-OCH₃ 5-OCF₃Ia.614 CF₃ H 3-CH₃ 4-OCH₃ 5-OCF₃ Ia.615 CF₃ H 3-CF₃ 4-OCH₃ 5-OCF₃ Ia.616CF₃ H 3-OCH₃ 4-OCH₃ 5-OCF₃ Ia.617 CF₃ H 3-OCF₃ 4-OCH₃ 5-OCF₃ Ia.618 CF₃H 3-fluoro 4-OCF₃ 5-fluoro Ia.619 CF₃ H 3-chloro 4-OCF₃ 5-fluoro Ia.620CF₃ H 3-CN 4-OCF₃ 5-fluoro Ia.621 CF₃ H 3-CH₃ 4-OCF₃ 5-fluoro Ia.622 CF₃H 3-CF₃ 4-OCF₃ 5-fluoro Ia.623 CF₃ H 3-OCH₃ 4-OCF₃ 5-fluoro Ia.624 CF₃ H3-OCF₃ 4-OCF₃ 5-fluoro Ia.625 CF₃ H 3-fluoro 4-OCF₃ 5-chloro Ia.626 CF₃H 3-chloro 4-OCF₃ 5-chloro Ia.627 CF₃ H 3-CN 4-OCF₃ 5-chloro Ia.628 CF₃H 3-CH₃ 4-OCF₃ 5-chloro Ia.629 CF₃ H 3-CF₃ 4-OCF₃ 5-chloro Ia.630 CF₃ H3-OCH₃ 4-OCF₃ 5-chloro Ia.631 CF₃ H 3-OCF₃ 4-OCF₃ 5-chloro Ia.632 CF₃ H3-fluoro 4-OCF₃ 5-CN Ia.633 CF₃ H 3-chloro 4-OCF₃ 5-CN Ia.634 CF₃ H 3-CN4-OCF₃ 5-CN Ia.635 CF₃ H 3-CH₃ 4-OCF₃ 5-CN Ia.636 CF₃ H 3-CF₃ 4-OCF₃5-CN Ia.637 CF₃ H 3-OCH₃ 4-OCF₃ 5-CN Ia.638 CF₃ H 3-OCF₃ 4-OCF₃ 5-CNIa.639 CF₃ H 3-fluoro 4-OCF₃ 5-CH₃ Ia.640 CF₃ H 3-chloro 4-OCF₃ 5-CH₃Ia.641 CF₃ H 3-CN 4-OCF₃ 5-CH₃ Ia.642 CF₃ H 3-CH₃ 4-OCF₃ 5-CH₃ Ia.643CF₃ H 3-CF3 4-OCF₃ 5-CH₃ Ia.644 CF₃ H 3-OCH₃ 4-OCF₃ 5-CH₃ Ia.645 CF₃ H3-OCF₃ 4-OCF₃ 5-CH₃ Ia.646 CF₃ H 3-fluoro 4-OCF₃ 5-CF₃ Ia.647 CF₃ H3-chloro 4-OCF₃ 5-CF₃ Ia.648 CF₃ H 3-CN 4-OCF₃ 5-CF₃ Ia.649 CF₃ H 3-CH₃4-OCF₃ 5-CF₃ Ia.650 CF₃ H 3-CF₃ 4-OCF₃ 5-CF₃ Ia.651 CF₃ H 3-OCH₃ 4-OCF₃5-CF₃ Ia.652 CF₃ H 3-OCF₃ 4-OCF₃ 5-CF₃ Ia.653 CF₃ H 3-fluoro 4-OCF₃5-OCH₃ Ia.654 CF₃ H 3-chloro 4-OCF₃ 5-OCH₃ Ia.655 CF₃ H 3-CN 4-OCF₃5-OCH₃ Ia.656 CF₃ H 3-CH₃ 4-OCF₃ 5-OCH₃ Ia.657 CF₃ H 3-CF₃ 4-OCF₃ 5-OCH₃Ia.658 CF₃ H 3-OCH₃ 4-OCF₃ 5-OCH₃ Ia.659 CF₃ H 3-OCF₃ 4-OCF₃ 5-OCH₃Ia.660 CF₃ H 3-fluoro 4-OCF₃ 5-OCF₃ Ia.661 CF₃ H 3-chloro 4-OCF₃ 5-OCF₃Ia.662 CF₃ H 3-CN 4-OCF₃ 5-OCF₃ Ia.663 CF₃ H 3-CH₃ 4-OCF₃ 5-OCF₃ Ia.664CF₃ H 3-CF₃ 4-OCF₃ 5-OCF₃ Ia.665 CF₃ H 3-OCH₃ 4-OCF₃ 5-OCF₃ Ia.666 CF₃ H3-OCF₃ 4-OCF₃ 5-OCF₃ Ia.667 CF₃ H 2-fluoro 4-fluoro 5-fluoro 110-113Ia.668 CF₃ H 2-fluoro 4-fluoro 5-chloro Ia.669 CF₃ H 2-fluoro 4-fluoro5-CN Ia.670 CF₃ H 2-fluoro 4-fluoro 5-CH₃ Ia.671 CF₃ H 2-fluoro 4-fluoro5-CF₃ Ia.672 CF₃ H 2-fluoro 4-fluoro 5-OCH₃ Ia.673 CF₃ H 2-fluoro4-fluoro 5-OCF₃ Ia.674 CF₃ H 2-chloro 4-fluoro 5-fluoro Ia.675 CF₃ H2-chloro 4-fluoro 5-chloro Ia.676 CF₃ H 2-chloro 4-fluoro 5-CN Ia.677CF₃ H 2-chloro 4-fluoro 5-CH₃ Ia.678 CF₃ H 2-chloro 4-fluoro 5-CF₃Ia.679 CF₃ H 2-chloro 4-fluoro 5-OCH₃ Ia.680 CF₃ H 2-chloro 4-fluoro5-OCF₃ Ia.681 CF₃ H 2-CN 4-fluoro 5-fluoro Ia.682 CF₃ H 2-CN 4-fluoro5-chloro Ia.683 CF₃ H 2-CN 4-fluoro 5-CN Ia.684 CF₃ H 2-CN 4-fluoro5-CH₃ Ia.685 CF₃ H 2-CN 4-fluoro 5-CF₃ Ia.686 CF₃ H 2-CN 4-fluoro 5-OCH₃Ia.687 CF₃ H 2-CN 4-fluoro 5-OCF₃ Ia.688 CF₃ H 2-methyl 4-fluoro5-fluoro Ia.689 CF₃ H 2-methyl 4-fluoro 5-chloro Ia.690 CF₃ H 2-methyl4-fluoro 5-CN Ia.691 CF₃ H 2-methyl 4-fluoro 5-CH₃ Ia.692 CF₃ H 2-methyl4-fluoro 5-CF₃ Ia.693 CF₃ H 2-methyl 4-fluoro 5-OCH₃ Ia.694 CF₃ H2-methyl 4-fluoro 5-OCF₃ Ia.695 CF₃ H 2-CF₃ 4-fluoro 5-fluoro Ia.696 CF₃H 2-CF₃ 4-fluoro 5-chloro Ia.697 CF₃ H 2-CF₃ 4-fluoro 5-CN Ia.698 CF₃ H2-CF₃ 4-fluoro 5-CH₃ Ia.699 CF₃ H 2-CF₃ 4-fluoro 5-CF₃ Ia.700 CF₃ H2-CF₃ 4-fluoro 5-OCH₃ Ia.701 CF₃ H 2-CF₃ 4-fluoro 5-OCF₃ Ia.702 CF₃ H2-OCH₃ 4-fluoro 5-fluoro Ia.703 CF₃ H 2-OCH₃ 4-fluoro 5-chloro Ia.704CF₃ H 2-OCH₃ 4-fluoro 5-CN Ia.705 CF₃ H 2-OCH₃ 4-fluoro 5-CH₃ Ia.706 CF₃H 2-OCH₃ 4-fluoro 5-CF₃ Ia.707 CF₃ H 2-OCH₃ 4-fluoro 5-OCH₃ Ia.708 CF₃ H2-OCH₃ 4-fluoro 5-OCF₃ Ia.709 CF₃ H 2-OCF₃ 4-fluoro 5-fluoro Ia.710 CF₃H 2-OCF₃ 4-fluoro 5-chloro Ia.711 CF₃ H 2-OCF₃ 4-fluoro 5-CN Ia.712 CF₃H 2-OCF₃ 4-fluoro 5-CH₃ Ia.713 CF₃ H 2-OCF₃ 4-fluoro 5-CF₃ Ia.714 CF₃ H2-OCF₃ 4-fluoro 5-OCH₃ Ia.715 CF₃ H 2-OCF₃ 4-fluoro 5-OCF₃ Ia.716 CF₃ H2-fluoro 4-chloro 5-fluoro Ia.717 CF₃ H 2-fluoro 4-chloro 5-chloroIa.718 CF₃ H 2-fluoro 4-chloro 5-CN Ia.719 CF₃ H 2-fluoro 4-chloro 5-CH₃106-108 Ia.720 CF₃ H 2-fluoro 4-chloro 5-CF₃ Ia.721 CF₃ H 2-fluoro4-chloro 5-OCH₃ 119-121 Ia.722 CF₃ H 2-fluoro 4-chloro 5-OCF₃ Ia.723 CF₃H 2-chloro 4-chloro 5-fluoro Ia.724 CF₃ H 2-chloro 4-chloro 5-chloroIa.725 CF₃ H 2-chloro 4-chloro 5-CN Ia.726 CF₃ H 2-chloro 4-chloro 5-CH₃Ia.727 CF₃ H 2-chloro 4-chloro 5-CF₃ Ia.728 CF₃ H 2-chloro 4-chloro5-OCH₃ Ia.729 CF₃ H 2-chloro 4-chloro 5-OCF₃ Ia.730 CF₃ H 2-CN 4-chloro5-fluoro Ia.731 CF₃ H 2-CN 4-chloro 5-chloro Ia.732 CF₃ H 2-CN 4-chloro5-CN Ia.733 CF₃ H 2-CN 4-chloro 5-CH₃ Ia.734 CF₃ H 2-CN 4-chloro 5-CF₃Ia.735 CF₃ H 2-CN 4-chloro 5-OCH₃ Ia.736 CF₃ H 2-CN 4-chloro 5-OCF₃Ia.737 CF₃ H 2-methyl 4-chloro 5-fluoro Ia.738 CF₃ H 2-methyl 4-chloro5-chloro Ia.739 CF₃ H 2-methyl 4-chloro 5-CN Ia.740 CF₃ H 2-methyl4-chloro 5-CH₃ Ia.741 CF₃ H 2-methyl 4-chloro 5-CF₃ Ia.742 CF₃ H2-methyl 4-chloro 5-OCH₃ Ia.743 CF₃ H 2-methyl 4-chloro 5-OCF₃ Ia.744CF₃ H 2-CF₃ 4-chloro 5-fluoro Ia.745 CF₃ H 2-CF₃ 4-chloro 5-chloroIa.746 CF₃ H 2-CF₃ 4-chloro 5-CN Ia.747 CF₃ H 2-CF₃ 4-chloro 5-CH₃Ia.748 CF₃ H 2-CF₃ 4-chloro 5-CF₃ Ia.749 CF₃ H 2-CF₃ 4-chloro 5-OCH₃Ia.750 CF₃ H 2-CF₃ 4-chloro 5-OCF₃ Ia.751 CF₃ H 2-OCH₃ 4-chloro 5-fluoroIa.752 CF₃ H 2-OCH₃ 4-chloro 5-chloro Ia.753 CF₃ H 2-OCH₃ 4-chloro 5-CNIa.754 CF₃ H 2-OCH₃ 4-chloro 5-CH₃ Ia.755 CF₃ H 2-OCH₃ 4-chloro 5-CF₃Ia.756 CF₃ H 2-OCH₃ 4-chloro 5-OCH₃ Ia.757 CF₃ H 2-OCH₃ 4-chloro 5-OCF₃Ia.758 CF₃ H 2-OCF₃ 4-chloro 5-fluoro Ia.759 CF₃ H 2-OCF₃ 4-chloro5-chloro Ia.760 CF₃ H 2-OCF₃ 4-chloro 5-CN Ia.761 CF₃ H 2-OCF₃ 4-chloro5-CH₃ Ia.762 CF₃ H 2-OCF₃ 4-chloro 5-CF₃ Ia.763 CF₃ H 2-OCF₃ 4-chloro5-OCH₃ Ia.764 CF₃ H 2-OCF₃ 4-chloro 5-OCF₃ Ia.765 CF₃ H 2-fluoro 4-CN5-fluoro Ia.766 CF₃ H 2-fluoro 4-CN 5-chloro Ia.767 CF₃ H 2-fluoro 4-CN5-CN Ia.768 CF₃ H 2-fluoro 4-CN 5-CH₃ Ia.769 CF₃ H 2-fluoro 4-CN 5-CF₃Ia.770 CF₃ H 2-fluoro 4-CN 5-OCH₃ Ia.771 CF₃ H 2-fluoro 4-CN 5-OCF₃Ia.772 CF₃ H 2-chloro 4-CN 5-fluoro Ia.773 CF₃ H 2-chloro 4-CN 5-chloroIa.774 CF₃ H 2-chloro 4-CN 5-CN Ia.775 CF₃ H 2-chloro 4-CN 5-CH₃ Ia.776CF₃ H 2-chloro 4-CN 5-CF₃ Ia.777 CF₃ H 2-chloro 4-CN 5-OCH₃ Ia.778 CF₃ H2-chloro 4-CN 5-OCF₃ Ia.779 CF₃ H 2-CN 4-CN 5-fluoro Ia.780 CF₃ H 2-CN4-CN 5-chloro Ia.781 CF₃ H 2-CN 4-CN 5-CN Ia.782 CF₃ H 2-CN 4-CN 5-CH₃Ia.783 CF₃ H 2-CN 4-CN 5-CF₃ Ia.784 CF₃ H 2-CN 4-CN 5-OCH₃ Ia.785 CF₃ H2-CN 4-CN 5-OCF₃ Ia.786 CF₃ H 2-methyl 4-CN 5-fluoro Ia.787 CF₃ H2-methyl 4-CN 5-chloro Ia.788 CF₃ H 2-methyl 4-CN 5-CN Ia.789 CF₃ H2-methyl 4-CN 5-CH₃ Ia.790 CF₃ H 2-methyl 4-CN 5-CF₃ Ia.791 CF₃ H2-methyl 4-CN 5-OCH₃ Ia.792 CF₃ H 2-methyl 4-CN 5-OCF₃ Ia.793 CF₃ H2-CF₃ 4-CN 5-fluoro Ia.794 CF₃ H 2-CF₃ 4-CN 5-chloro Ia.795 CF₃ H 2-CF₃4-CN 5-CN Ia.796 CF₃ H 2-CF₃ 4-CN 5-CH₃ Ia.797 CF₃ H 2-CF₃ 4-CN 5-CF₃Ia.798 CF₃ H 2-CF₃ 4-CN 5-OCH₃ Ia.799 CF₃ H 2-CF₃ 4-CN 5-OCF₃ Ia.800 CF₃H 2-OCH₃ 4-CN 5-fluoro Ia.801 CF₃ H 2-OCH₃ 4-CN 5-chloro Ia.802 CF₃ H2-OCH₃ 4-CN 5-CN Ia.803 CF₃ H 2-OCH₃ 4-CN 5-CH₃ Ia.804 CF₃ H 2-OCH₃ 4-CN5-CF₃ Ia.805 CF₃ H 2-OCH₃ 4-CN 5-OCH₃ Ia.806 CF₃ H 2-OCH₃ 4-CN 5-OCF₃Ia.807 CF₃ H 2-OCF₃ 4-CN 5-fluoro Ia.808 CF₃ H 2-OCF₃ 4-CN 5-chloroIa.809 CF₃ H 2-OCF₃ 4-CN 5-CN Ia.810 CF₃ H 2-OCF₃ 4-CN 5-CH₃ Ia.811 CF₃H 2-OCF₃ 4-CN 5-CF₃ Ia.812 CF₃ H 2-OCF₃ 4-CN 5-OCH₃ Ia.813 CF₃ H 2-OCF₃4-CN 5-OCF₃ Ia.814 CF₃ H 2-fluoro 4-CH₃ 5-fluoro Ia.815 CF₃ H 2-fluoro4-CH₃ 5-chloro Ia.816 CF₃ H 2-fluoro 4-CH₃ 5-CN Ia.817 CF₃ H 2-fluoro4-CH₃ 5-CH₃ Ia.818 CF₃ H 2-fluoro 4-CH₃ 5-CF₃ Ia.819 CF₃ H 2-fluoro4-CH₃ 5-OCH₃ Ia.820 CF₃ H 2-fluoro 4-CH₃ 5-OCF₃ Ia.821 CF₃ H 2-chloro4-CH₃ 5-fluoro Ia.822 CF₃ H 2-chloro 4-CH₃ 5-chloro Ia.823 CF₃ H2-chloro 4-CH₃ 5-CN Ia.824 CF₃ H 2-chloro 4-CH₃ 5-CH₃ Ia.825 CF₃ H2-chloro 4-CH₃ 5-CF₃ Ia.826 CF₃ H 2-chloro 4-CH₃ 5-OCH₃ Ia.827 CF₃ H2-chloro 4-CH₃ 5-OCF₃ Ia.828 CF₃ H 2-CN 4-CH₃ 5-fluoro Ia.829 CF₃ H 2-CN4-CH₃ 5-chloro Ia.830 CF₃ H 2-CN 4-CH₃ 5-CN Ia.831 CF₃ H 2-CN 4-CH₃5-CH₃ Ia.832 CF₃ H 2-CN 4-CH₃ 5-CF₃ Ia.833 CF₃ H 2-CN 4-CH₃ 5-OCH₃Ia.834 CF₃ H 2-CN 4-CH₃ 5-OCF₃ Ia.835 CF₃ H 2-methyl 4-CH₃ 5-fluoroIa.836 CF₃ H 2-methyl 4-CH₃ 5-chloro Ia.837 CF₃ H 2-methyl 4-CH₃ 5-CNIa.838 CF₃ H 2-methyl 4-CH₃ 5-CH₃ Ia.839 CF₃ H 2-methyl 4-CH₃ 5-CF₃Ia.840 CF₃ H 2-methyl 4-CH₃ 5-OCH₃ Ia.841 CF₃ H 2-methyl 4-CH₃ 5-OCF₃Ia.842 CF₃ H 2-CF₃ 4-CH₃ 5-fluoro Ia.843 CF₃ H 2-CF₃ 4-CH₃ 5-chloroIa.844 CF₃ H 2-CF₃ 4-CH₃ 5-CN Ia.845 CF₃ H 2-CF₃ 4-CH₃ 5-CH₃ Ia.846 CF₃H 2-CF₃ 4-CH₃ 5-CF₃ Ia.847 CF₃ H 2-CF₃ 4-CH₃ 5-OCH₃ Ia.848 CF₃ H 2-CF₃4-CH₃ 5-OCF₃ Ia.849 CF₃ H 2-OCH₃ 4-CH₃ 5-fluoro Ia.850 CF₃ H 2-OCH₃4-CH₃ 5-chloro Ia.851 CF₃ H 2-OCH₃ 4-CH₃ 5-CN Ia.852 CF₃ H 2-OCH₃ 4-CH₃5-CH₃ Ia.853 CF₃ H 2-OCH₃ 4-CH₃ 5-CF₃ Ia.854 CF₃ H 2-OCH₃ 4-CH₃ 5-OCH₃Ia.855 CF₃ H 2-OCH₃ 4-CH₃ 5-OCF₃ Ia.856 CF₃ H 2-OCF₃ 4-CH₃ 5-fluoroIa.857 CF₃ H 2-OCF₃ 4-CH₃ 5-chloro Ia.858 CF₃ H 2-OCF₃ 4-CH₃ 5-CN Ia.859CF₃ H 2-OCF₃ 4-CH₃ 5-CH₃ Ia.860 CF₃ H 2-OCF₃ 4-CH₃ 5-CF₃ Ia.861 CF₃ H2-OCF₃ 4-CH₃ 5-OCH₃ Ia.862 CF₃ H 2-OCF₃ 4-CH₃ 5-OCF₃ Ia.863 CF₃ H2-fluoro 4-CF₃ 5-fluoro Ia.864 CF₃ H 2-fluoro 4-CF₃ 5-chloro Ia.865 CF₃H 2-fluoro 4-CF₃ 5-CN Ia.866 CF₃ H 2-fluoro 4-CF₃ 5-CH₃ Ia.867 CF₃ H2-fluoro 4-CF₃ 5-CF₃ Ia.868 CF₃ H 2-fluoro 4-CF₃ 5-OCH₃ Ia.869 CF₃ H2-fluoro 4-CF₃ 5-OCF₃ Ia.870 CF₃ H 2-chloro 4-CF₃ 5-fluoro Ia.871 CF₃ H2-chloro 4-CF₃ 5-chloro Ia.872 CF₃ H 2-chloro 4-CF₃ 5-CN Ia.873 CF₃ H2-chloro 4-CF₃ 5-CH₃ Ia.874 CF₃ H 2-chloro 4-CF₃ 5-CF₃ Ia.875 CF₃ H2-chloro 4-CF₃ 5-OCH₃ Ia.876 CF₃ H 2-chloro 4-CF₃ 5-OCF₃ Ia.877 CF₃ H2-CN 4-CF₃ 5-fluoro Ia.878 CF₃ H 2-CN 4-CF₃ 5-chloro Ia.879 CF₃ H 2-CN4-CF₃ 5-CN Ia.880 CF₃ H 2-CN 4-CF₃ 5-CH₃ Ia.881 CF₃ H 2-CN 4-CF₃ 5-CF₃Ia.882 CF₃ H 2-CN 4-CF₃ 5-OCH₃ Ia.883 CF₃ H 2-CN 4-CF₃ 5-OCF₃ Ia.884 CF₃H 2-methyl 4-CF₃ 5-fluoro Ia.885 CF₃ H 2-methyl 4-CF₃ 5-chloro Ia.886CF₃ H 2-methyl 4-CF₃ 5-CN Ia.887 CF₃ H 2-methyl 4-CF₃ 5-CH₃ Ia.888 CF₃ H2-methyl 4-CF₃ 5-CF₃ Ia.889 CF₃ H 2-methyl 4-CF₃ 5-OCH₃ Ia.890 CF₃ H2-methyl 4-CF₃ 5-OCF₃ Ia.891 CF₃ H 2-CF₃ 4-CF₃ 5-fluoro Ia.892 CF₃ H2-CF₃ 4-CF₃ 5-chloro Ia.893 CF₃ H 2-CF₃ 4-CF₃ 5-CN Ia.894 CF₃ H 2-CF₃4-CF₃ 5-CH₃ Ia.895 CF₃ H 2-CF₃ 4-CF₃ 5-CF₃ Ia.896 CF₃ H 2-CF₃ 4-CF₃5-OCH₃ Ia.897 CF₃ H 2-CF₃ 4-CF₃ 5-OCF₃ Ia.898 CF₃ H 2-OCH₃ 4-CF₃5-fluoro Ia.899 CF₃ H 2-OCH₃ 4-CF₃ 5-chloro Ia.900 CF₃ H 2-OCH₃ 4-CF₃5-CN Ia.901 CF₃ H 2-OCH₃ 4-CF₃ 5-CH₃ Ia.902 CF₃ H 2-OCH₃ 4-CF₃ 5-CF₃Ia.903 CF₃ H 2-OCH₃ 4-CF₃ 5-OCH₃ Ia.904 CF₃ H 2-OCH₃ 4-CF₃ 5-OCF₃ Ia.905CF₃ H 2-OCF₃ 4-CF₃ 5-fluoro Ia.906 CF₃ H 2-OCF₃ 4-CF₃ 5-chloro Ia.907CF₃ H 2-OCF₃ 4-CF₃ 5-CN Ia.908 CF₃ H 2-OCF₃ 4-CF₃ 5-CH₃ Ia.909 CF₃ H2-OCF₃ 4-CF₃ 5-CF₃ Ia.910 CF₃ H 2-OCF₃ 4-CF₃ 5-OCH₃ Ia.911 CF₃ H 2-OCF₃4-CF₃ 5-OCF₃ Ia.912 CF₃ H 2-fluoro 4-OCH₃ 5-fluoro Ia.913 CF₃ H 2-fluoro4-OCH₃ 5-chloro Ia.914 CF₃ H 2-fluoro 4-OCH₃ 5-CN Ia.915 CF₃ H 2-fluoro4-OCH₃ 5-CH₃ Ia.916 CF₃ H 2-fluoro 4-OCH₃ 5-CF₃ Ia.917 CF₃ H 2-fluoro4-OCH₃ 5-OCH₃ Ia.918 CF₃ H 2-fluoro 4-OCH₃ 5-OCF₃ Ia.919 CF₃ H 2-chloro4-OCH₃ 5-fluoro Ia.920 CF₃ H 2-chloro 4-OCH₃ 5-chloro Ia.921 CF₃ H2-chloro 4-OCH₃ 5-CN Ia.922 CF₃ H 2-chloro 4-OCH₃ 5-CH₃ Ia.923 CF₃ H2-chloro 4-OCH₃ 5-CF₃ Ia.924 CF₃ H 2-chloro 4-OCH₃ 5-OCH₃ Ia.925 CF₃ H2-chloro 4-OCH₃ 5-OCF₃ Ia.926 CF₃ H 2-CN 4-OCH₃ 5-fluoro Ia.927 CF₃ H2-CN 4-OCH₃ 5-chloro Ia.928 CF₃ H 2-CN 4-OCH₃ 5-CN Ia.929 CF₃ H 2-CN4-OCH₃ 5-CH₃ Ia.930 CF₃ H 2-CN 4-OCH₃ 5-CF₃ Ia.931 CF₃ H 2-CN 4-OCH₃5-OCH₃ Ia.932 CF₃ H 2-CN 4-OCH₃ 5-OCF₃ Ia.933 CF₃ H 2-methyl 4-OCH₃5-fluoro Ia.934 CF₃ H 2-methyl 4-OCH₃ 5-chloro Ia.935 CF₃ H 2-methyl4-OCH₃ 5-CN Ia.936 CF₃ H 2-methyl 4-OCH₃ 5-CH₃ Ia.937 CF₃ H 2-methyl4-OCH₃ 5-CF₃ Ia.938 CF₃ H 2-methyl 4-OCH₃ 5-OCH₃ Ia.939 CF₃ H 2-methyl4-OCH₃ 5-OCF₃ Ia.940 CF₃ H 2-CF₃ 4-OCH₃ 5-fluoro Ia.941 CF₃ H 2-CF₃4-OCH₃ 5-chloro Ia.942 CF₃ H 2-CF₃ 4-OCH₃ 5-CN Ia.943 CF₃ H 2-CF₃ 4-OCH₃5-CH₃ Ia.944 CF₃ H 2-CF₃ 4-OCH₃ 5-CF₃ Ia.945 CF₃ H 2-CF₃ 4-OCH₃ 5-OCH₃Ia.946 CF₃ H 2-CF₃ 4-OCH₃ 5-OCF₃ Ia.947 CF₃ H 2-OCH₃ 4-OCH₃ 5-fluoroIa.948 CF₃ H 2-OCH₃ 4-OCH₃ 5-chloro Ia.949 CF₃ H 2-OCH₃ 4-OCH₃ 5-CNIa.950 CF₃ H 2-OCH₃ 4-OCH₃ 5-CH₃ Ia.951 CF₃ H 2-OCH₃ 4-OCH₃ 5-CF₃ Ia.952CF₃ H 2-OCH₃ 4-OCH₃ 5-OCH₃ Ia.953 CF₃ H 2-OCH₃ 4-OCH₃ 5-OCF₃ Ia.954 CF₃H 2-OCF₃ 4-OCH₃ 5-fluoro Ia.955 CF₃ H 2-OCF₃ 4-OCH₃ 5-chloro Ia.956 CF₃H 2-OCF₃ 4-OCH₃ 5-CN Ia.957 CF₃ H 2-OCF₃ 4-OCH₃ 5-CH₃ Ia.958 CF₃ H2-OCF₃ 4-OCH₃ 5-CF₃ Ia.959 CF₃ H 2-OCF₃ 4-OCH₃ 5-OCH₃ Ia.960 CF₃ H2-OCF₃ 4-OCH₃ 5-OCF₃ Ia.961 CF₃ H 2-fluoro 4-OCF₃ 5-fluoro Ia.962 CF₃ H2-fluoro 4-OCF₃ 5-chloro Ia.963 CF₃ H 2-fluoro 4-OCF₃ 5-CN Ia.964 CF₃ H2-fluoro 4-OCF₃ 5-CH₃ Ia.965 CF₃ H 2-fluoro 4-OCF₃ 5-CF₃ Ia.966 CF₃ H2-fluoro 4-OCF₃ 5-OCH₃ Ia.967 CF₃ H 2-fluoro 4-OCF₃ 5-OCF₃ Ia.968 CF₃ H2-chloro 4-OCF₃ 5-fluoro Ia.969 CF₃ H 2-chloro 4-OCF₃ 5-chloro Ia.970CF₃ H 2-chloro 4-OCF₃ 5-CN Ia.971 CF₃ H 2-chloro 4-OCF₃ 5-CH₃ Ia.972 CF₃H 2-chloro 4-OCF₃ 5-CF₃ Ia.973 CF₃ H 2-chloro 4-OCF₃ 5-OCH₃ Ia.974 CF₃ H2-chloro 4-OCF₃ 5-OCF₃ Ia.975 CF₃ H 2-CN 4-OCF₃ 5-fluoro Ia.976 CF₃ H2-CN 4-OCF₃ 5-chloro Ia.977 CF₃ H 2-CN 4-OCF₃ 5-CN Ia.978 CF₃ H 2-CN4-OCF₃ 5-CH₃ Ia.979 CF₃ H 2-CN 4-OCF₃ 5-CF₃ Ia.980 CF₃ H 2-CN 4-OCF₃5-OCH₃ Ia.981 CF₃ H 2-CN 4-OCF₃ 5-OCF₃ Ia.982 CF₃ H 2-methyl 4-OCF₃5-fluoro Ia.983 CF₃ H 2-methyl 4-OCF₃ 5-chloro Ia.984 CF₃ H 2-methyl4-OCF₃ 5-CN Ia.985 CF₃ H 2-methyl 4-OCF₃ 5-CH₃ Ia.986 CF₃ H 2-methyl4-OCF₃ 5-CF₃ Ia.987 CF₃ H 2-methyl 4-OCF₃ 5-OCH₃ Ia.988 CF₃ H 2-methyl4-OCF₃ 5-OCF₃ Ia.989 CF₃ H 2-CF₃ 4-OCF₃ 5-fluoro Ia.990 CF₃ H 2-CF₃4-OCF₃ 5-chloro Ia.991 CF₃ H 2-CF₃ 4-OCF₃ 5-CN Ia.992 CF₃ H 2-CF₃ 4-OCF₃5-CH₃ Ia.993 CF₃ H 2-CF₃ 4-OCF₃ 5-CF₃ Ia.994 CF₃ H 2-CF₃ 4-OCF₃ 5-OCH₃Ia.995 CF₃ H 2-CF₃ 4-OCF₃ 5-OCF₃ Ia.996 CF₃ H 2-OCH₃ 4-OCF₃ 5-fluoroIa.997 CF₃ H 2-OCH₃ 4-OCF₃ 5-chloro Ia.998 CF₃ H 2-OCH₃ 4-OCF₃ 5-CNIa.999 CF₃ H 2-OCH₃ 4-OCF₃ 5-CH₃ Ia.1000 CF₃ H 2-OCH₃ 4-OCF₃ 5-CF₃Ia.1001 CF₃ H 2-OCH₃ 4-OCF₃ 5-OCH₃ Ia.1002 CF₃ H 2-OCH₃ 4-OCF₃ 5-OCF₃Ia.1003 CF₃ H 2-OCF₃ 4-OCF₃ 5-fluoro Ia.1004 CF₃ H 2-OCF₃ 4-OCF₃5-chloro Ia.1005 CF₃ H 2-OCF₃ 4-OCF₃ 5-CN Ia.1006 CF₃ H 2-OCF₃ 4-OCF₃5-CH₃ Ia.1007 CF₃ H 2-OCF₃ 4-OCF₃ 5-CF₃ Ia.1008 CF₃ H 2-OCF₃ 4-OCF₃5-OCH₃ Ia.1009 CF₃ H 2-OCF₃ 4-OCF₃ 5-OCF₃

Particular preference is furthermore given to1-methylpyrazol-4-ylcarboxanilides of the formulae Ib to If, inparticular to

-   -   the compounds Ib.1 to Ib.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R² is        fluorine:

-   -   the compounds Ic.1 to Ic.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R² is        chlorine:

-   -   the compounds Id.1 to Id.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R¹ is        difluoromethyl:

Id

Compound M.p. [° C.] No. Id. 721 150-152 No. Id. 719 120-122 No. Id. 667122-125 No. Id. 344 156-158

-   -   the compounds Ie.1 to Ie.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R¹ is        difluoromethyl and R² is fluorine:

-   -   the compounds If.1 to If.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R¹ is        difluoromethyl and R² is chlorine:

-   -   the compounds Ig.1 to Ig.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R¹ is        fluoromethyl:

Ig

Compound M.p. [° C.] No. Ig. 344 152-156 No. Ig. 1 126-129

-   -   the compounds Ih.1 to Ih.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R¹ is        CF₂Cl:

Ih

Compound M.p. [° C.] No. Ih. 344 158-161

-   -   the compounds Ij.1 to Ij.1009 which differ from the        corresponding compounds Ia.1 to Ia.1009 only in that R¹ is        chlorofluoromethyl:

Ij

Compound M.p. [° C.] No. Ij. 344 154-157

Very particular preference is given to

N-(2′-fluoro-4′-chloro-5′-methoxybiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′-fluoro-4′-chloro-5′-methylbiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoro-methyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-tri-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′-fluoro-4′-chloro-5′-methoxy-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-tri-fluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′-fluoro-4′-chloro-5′-methylbiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoro-methyl-1-methyl-1H-pyrazole-4-carboxamideandN-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.

Preference is given to mixtures of a compound of the formula I with atleast one active compound selected from the group of the A) azoles.

Preference is also given to mixtures of a compound of the formula I withat least one active compound selected from the group of the B)strobilurins.

Preference is given to mixtures of a compound of the formula I with atleast one active compound selected from the group of the C)carboxamides.

Preference is furthermore also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe D) heterocyclic compounds.

Preference is furthermore also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe E) carbamates.

Preference is furthermore also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe F) other fungicides.

Preference is furthermore also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe A) azoles selected from the group consisting of cyproconazole,difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol,metconazole, myclobutanil, penconazole, propiconazole, prothioconazole,triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole,prochloraz, cyazofamid, benomyl, carbendazim and ethaboxam.

Particular preference is also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe A) azoles selected from the group consisting of cyproconazole,difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol,metconazole, myclobutanil, propiconazole, prothioconazole, triadimefon,triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz,cyazofamid, benomyl and carbendazim.

Very particular preference is also given to mixtures of a compound ofthe formula I with at least one active compound selected from the groupof the A) azoles selected from the group consisting of epoxiconazole,fluquinconazole, flutriafol, metconazole, tebuconazole, triticonazole,prochloraz and carbendazim.

Preference is also given to mixtures of a compound of the formula I withat least one active compound selected from the group of the B)strobilurins selected from the group consisting of azoxystrobin,dimoxystrobin, fluoxastrobin, kresoxim-methyl, orysastrobin,picoxystrobin, pyraclostrobin and trifloxystrobin.

Particular preference is also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe B) strobilurins selected from the group consisting ofkresoxim-methyl, orysastrobin and pyraclostrobin.

Very particular preference is also given to mixtures of a compound ofthe formula I with pyraclostrobin.

Preference is also given to mixtures of a compound of the formula I withat least one active compound selected from the group of the C)carboxamides selected from the group consisting of fenhexamid,metalaxyl, mefenoxam, ofurace, dimethomorph, flumorph, fluopicolide(picobenzamid), zoxamide, carpropamid and mandipropamid.

Particular preference is also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe C) carboxamides selected from the group consisting of fenhexamid,metalaxyl, mefenoxam, ofurace, dimethomorph, zoxamide and carpropamid.

Preference is also given to mixtures of a compound of the formula I withat least one active compound selected from the group of the D)heterocyclic compounds selected from the group consisting of fluazinam,cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine,fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin,iprodione, vinclozolin, famoxadone, fenamidone, probenazole,5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine,proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil andquinoxyfen, in particular fluazinam, cyprodinil, fenarimol, mepanipyrim,pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph,tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone,probenazole, proquinazid, acibenzolar-S-methyl, captafol, folpet,fenoxanil and quinoxyfen.

Particular preference is also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe D) heterocyclic compounds selected from the group consisting ofpyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione,vinclozolin,5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluoro-phenyl)-[1,2,4]triazolo[1,5-a]pyrimidineand quinoxyfen, in particular pyrimethanil, dodemorph, fenpropimorph,tridemorph, iprodione, vinclozolin and quinoxyfen.

Preference is also given to mixtures of a compound of the formula I withat least one active compound selected from the group of the E)carbamates selected from the group consisting of mancozeb, metiram,propineb, thiram, iprovalicarb, flubenthiavalicarb and propamocarb.

Particular preference is also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe E) carbamates selected from the group consisting of mancozeb andmetiram.

Preference is also given to mixtures of a compound of the formula I withat least one active compound selected from the group of the F) otherfungicides selected from the group consisting of dithianon, fentinsalts, such as fentin acetate, fosetyl, fosetyl-aluminum, phosphorousacid and its salts, chlorothalonil, dichlofluanid, thiophanate-methyl,copper acetate, copper hydroxide, copper oxychloride, basic coppersulfate, sulfur, cymoxanil, metrafenone and spiroxamine.

Particular preference is also given to mixtures of a compound of theformula I with at least one active compound selected from the group ofthe F) other fungicides selected from the group consisting ofphosphorous acid and its salts, chlorothalonil and metrafenone.

Preference is also given to three-component mixtures of one compound ofthe formula I with two of the active compounds II mentioned above.

Preferred active compound combinations are listed in Tables 3 to 9below:

TABLE 3 Active compound combinations of compounds I with activecompounds II of group A): Mixture Compound of the formula I (X = oxygen)Active compound II No. A.1 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F epoxiconazole No. A.2 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.3 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.4 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.5 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.6 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.7 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.8 R¹ = CHF₂; R² = Cl; R⁶ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.9 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.10 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.11 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.12 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.13 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.14 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.15 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.16 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.17 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.18 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.19 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.20 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.21 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.22 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.23 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.24 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fepoxiconazole No. A.25 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.26 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.27 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.28 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.29 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.30 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.31 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.32 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.33 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.34 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.35 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.36 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.37 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.38 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.39 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.40 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.41 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.42 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.43 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.44 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.45 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.46 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.47 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.48 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetconazole No. A.49 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.50 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.51 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.52 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.53 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.54 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.55 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.56 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.57 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.58 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.59 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.60 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.61 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.62 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.63 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.64 R¹ = CH₂F; R² - H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.65 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.66 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No, A.67 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R^(&) = 5-Ftebuconazole No. A.68 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁶ = 5-Ftebuconazole No. A.69 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.70 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.71 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.72 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftebuconazole No. A.73 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffluquinconazole No. A.74 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffluquinconazole No. A.75 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffluquinconazole No. A.76 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffluquinconazole No. A.77 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F fluquinconazole No. A.78 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F fluquinconazole No. A.79 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F fluquinconazole No. A.80 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁶= 5-F fluquinconazole No. A.81 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.82 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.83 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.84 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.85 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.86 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.87 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.88 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F fluquinconazole No. A.89 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F fluquinconazole No. A.90 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F fluquinconazole No. A.91 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F fluquinconazole No. A.92 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴= 4-F; R⁵ = 5-F fluquinconazole No. A.93 R¹ = CF₂Cl; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F fluquinconazole No. A.94 Ri = CF₃; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F fluquinconazole No. A.95 R¹ = CF₃; R² = F; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F fluquinconazole No. A.96 R¹ = CF₃; R² = Cl; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F fluquinconazole No. A.97 R¹ = CH₃; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F flutriafol No. A.98 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F flutriafol No. A.99 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F flutriafol No. A.100 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵= 5-F flutriafol No. A.101 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F flutriafol No. A.102 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.103 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.104 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.105 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.106 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.107 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.108 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.109 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.110 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.111 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.112 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.113 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.114 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.115 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.116 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.117 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.118 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.119 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.120 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fflutriafol No. A.121 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.122 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.123 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.124 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.125 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.126 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.127 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.128 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.129 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.130 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.131 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.132 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.133 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.134 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.135 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.136 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.137 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.138 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.139 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.140 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.141 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.142 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftriticonazole No. A.143 R¹ = CF₃; R² = F; R^(J) = 2-F; R⁴ = 4-F; R⁵ =5-F triticonazole No. A.144 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F triticonazole No. A.145 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁶ =5-F prochloraz No. A.146 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.147 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.148 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.149 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.150 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.151 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.152 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.153 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.154 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.155 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.156 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.157 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.158 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.159 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.160 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.161 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.162 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.163 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.164 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.165 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.166 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.167 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.168 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fprochloraz No. A.169 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.170 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.171 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.172 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.173 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.174 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.175 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.176 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.177 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.178 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.179 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.180 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.181 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F;. R⁵ = 5-Fcarbendazim No. A.182 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.183 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.184 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.185 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.186 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.187 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.188 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.189 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.190 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.191 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim No. A.192 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fcarbendazim

TABLE 4 Active compound combinations of compounds I with activecompounds II of group B): Active compound Mixture Compounds of theformula I (X = oxygen) II No. B.1 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.2 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.3 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.4 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.5 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.6 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.7 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.8 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.9 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.10 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.11 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.12 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.13 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.14 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.15 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.16 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F kresoxim-methyl No. B.17 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F kresoxim-methyl No. B.18 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F kresoxim-methyl No. B.19 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F kresoxim-methyl No. B.20 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴= 4-F; R⁵ = 5-F kresoxim-methyl No. B.21 R¹ = CF₂Cl; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F kresoxim-methyl No. B.22 R¹ = CF₃; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F kresoxim-methyl No. B.23 R¹ = CF₃; R² = F; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F kresoxim-methyl No. B.24 R¹ = CF₃; R² = Cl; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F kresoxim-methyl No. B.25 R¹ = CH₃; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.26 R¹ = CH₃; R² = F; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.27 R¹ = CH₃; R² = Cl; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.28 R¹ = CH₂F; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.29 R¹ = CHFCl; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.30 R¹ = CHF₂; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.31 R¹ = CHF₂; R² = F; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.32 R¹ = CHF₂; R² = Cl; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.33 R¹ = CF₂Cl; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.34 R¹ = CF₃; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.35 R¹ = CF₃; R² = F; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.36 R¹ = CF₃; R² = Cl; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.37 R¹ = CH₃; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.38 R¹ = CH₃; R² = F; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.39 R¹ = CH₃; R² = Cl; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.40 R¹ = CH₂F; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.41 R¹ = CHFCl; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.42 R¹ = CHF₂; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.43 R¹ = CHF₂; R² = F; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.44 R¹ = CHF₂; R² = Cl; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.45 R¹ = CF₂Cl; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.46 R¹ = CF₃; R² = H; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.47 R¹ = CF₃; R² = F; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.48 R¹ = CF₃; R² = Cl; R³ = 2-F;R⁴ = 4-F; R⁵ = 5-F pyraclostrobin No. B.49 R¹ = CH₃; R² = H; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F orysastrobin No. B.50 R¹ = CH₃; R² = F; R³ = 3-F; R⁴= 4-F; R⁵ = 5-F orysastrobin No. B.51 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.52 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.53 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.54 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.55 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.56 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.57 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.58 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.59 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.60 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.61 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.62 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.63 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.64 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.65 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.66 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.67 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.68 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.69 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.70 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.71 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin No. B.72 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ =4-F; R⁵ = 5-F orysastrobin

TABLE 5 Active compound combinations of compounds I with activecompounds II of group C): Active compound Mixture Compounds of theformula I (X = oxygen) II No. C.1 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F dimethomorph No. C.2 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F dimethomorph No. C.3 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.4 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.5 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.6 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.7 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.8 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.9 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.10 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.11 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.12 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.13 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.14 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.15 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.16 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.17 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.18 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.19 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.20 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.21 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.22 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.23 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph No. C.24 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdimethomorph

TABLE 6 Active compound combinations of compounds I with activecompounds II of group D): Mixture Compounds of the formula I (X =oxygen) Active compound II No. D.1 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F pyrimethanil No. D.2 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F pyrimethanil No. D.3 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.4 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.5 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.6 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.7 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.8 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.9 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.10 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.11 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.12 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.13 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.14 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.15 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.16 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.17 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.18 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.19 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.20 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.21 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.22 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.23 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.24 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fpyrimethanil No. D.25 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.26 R¹ = CH₃;R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.27 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.28 R¹ = CH₂F;R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.29 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.30 R¹ = CHF₂;R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.31 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.32 R¹ = CHF₂;R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.33 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.34 R¹ = CF₃;R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.35 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵= 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.36 R¹ = CF₃;R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.37 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵= 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.38 R¹ = CH₃;R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.39 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.40 R¹ = CH₂F;R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.41 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.42 R¹ = CHF₂;R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.43 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.44 R¹ = CHF₂;R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.45 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.46 R¹ = CF₃;R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.47 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵= 5-F 5-chloro-7-(4-methyl- piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]tri- azolo[1,5-a]pyrimidine No. D.48 R¹ = CF₃;R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6- trifluorophenyl)-[1,2,4]tri-azolo[1,5-a]pyrimidine No. D.49 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵= 5-F dodemorph No. D.50 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.51 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.52 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.53 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.54 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.55 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.56 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.57 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.58 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.59 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.60 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.61 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.62 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.63 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.64 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.65 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.66 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.67 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.68 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.69 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.70 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.71 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.72 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fdodemorph No. D.73 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.74 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.75 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.76 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.77 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.78 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.79 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.80 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.81 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.82 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.83 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.84 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.85 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.86 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.87 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.88 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.89 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.90 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.91 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.92 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.93 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.94 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.95 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.96 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ffenpropimorph No. D.97 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph No. D.98 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph No. D.99 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph No. R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.100 No. R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.101 No. R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.102 No. R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.103 No. R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.104 No. R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.105 No. R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.106 No. R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.107 No. R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.108 No. R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.109 No. R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.110 No. R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.111 No. R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.112 No. R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.113 No. R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.114 No. R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.115 No. R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.116 No. R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.117 No. R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.118 No. R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.119 No. R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Ftridemorph D.120 No. R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.121 No. R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.122 No. R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.123 No. R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.124 No. R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.125 No. R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.126 No. R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.127 No. R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.128 No. R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.129 No. R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.130 No. R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.131 No. R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.132 No. R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.133 No. R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.134 No. R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.135 No. R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.136 No. R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.137 No. R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.138 No. R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.139 No. R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.140 No. R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.141 No. R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.142 No. R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.143 No. R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fiprodione D.144 No. R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.145 No. R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.146 No. R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.147 No. R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.148 No. R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.149 No. R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.150 No. R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.151 No. R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.152 No. R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.153 No. R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.154 No. R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.155 No. R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.156 No. R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.157 No. R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.158 No. R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.159 No. R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.160 No. R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.161 No. R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.162 No. R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.163 No. R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.164 No. R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.165 No. R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.166 No. R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.167 No. R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fvinclozolin D.168

TABLE 7 Active compound combinations of compounds I with activecompounds II of group E): Active compound Mixture Compounds of theformula I (X = oxygen) II No. E.1 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F mancozeb No. E.2 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.3 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.4 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.5 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.6 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.7 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.8 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.9 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.10 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.11 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.12 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.13 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.14 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.15 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.16 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.17 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.18 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.19 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.20 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.21 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.22 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.23 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.24 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmancozeb No. E.25 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiramNo. E.26 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.27R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.28 R¹ =CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.29 R¹ = CHFCl;R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.30 R¹ = CHF₂; R² = H;R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.31 R¹ = CHF₂; R² = F; R³ =3-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.32 R¹ = CHF₂; R² = Cl; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F metiram No. E.33 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F metiram No. E.34 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵= 5-F metiram No. E.35 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetiram No. E.36 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-F metiramNo. E.37 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.38R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.39 R¹ =CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.40 R¹ = CH₂F;R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.41 R¹ = CHFCl; R² =H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.42 R¹ = CHF₂; R² = H; R³ =2-F; R⁴ = 4-F; R⁵ = 5-F metiram No. E.43 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴= 4-F; R⁵ = 5-F metiram No. E.44 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F;R⁵ = 5-F metiram No. E.45 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F metiram No. E.46 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetiram No. E.47 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiramNo. E.48 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F metiram

TABLE 8 Active compound combinations of compounds I with activecompounds II of group F): Active compound Mixture Compounds of theformula I (X = oxygen) II No. F.1 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F chlorothalonil No. F.2 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵= 5-F chlorothalonil No. F.3 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.4 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.5 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.6 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.7 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.8 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.9 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.10 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.11 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.12 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.13 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.14 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.15 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.16 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.17 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.18 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.19 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.20 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.21 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.22 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.23 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.24 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ =5-F chlorothalonil No. F.25 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F metrafenone No. F.26 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.27 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.28 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.29 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.30 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.31 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.32 R¹ = CHF₂; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.33 R¹ = CF₂Cl; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.34 R¹ = CF₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.35 R¹ = CF₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.36 R¹ = CF₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.37 R¹ = CH₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.38 R¹ = CH₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.39 R¹ = CH₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.40 R¹ = CH₂F; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.41 R¹ = CHFCl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.42 R¹ = CHF₂; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.43 R¹ = CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.44 R¹ = CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.45 R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.46 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.47 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.48 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-Fmetrafenone No. F.49 R¹ = CH₃; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fphosphorous acid No. F.50 R¹ = CH₃; R² = F; R³ = 3-F; R⁴ = 4-F; R⁵ = 5-Fphosphorous acid No. F.51 R¹ = CH₃; R² = Cl; R³ = 3-F; R⁴ = 4-F; R⁵ =5-F phosphorous acid No. F.52 R¹ = CH₂F; R² = H; R³ = 3-F; R⁴ = 4-F; R⁵= 5-F phosphorous acid No. F.53 R¹ = CHFCl; R² = H; R³ = 3-F; R⁴ = 4-F;R⁵ = 5-F phosphorous acid No. F.54 R¹ = CHF₂; R² = H; R³ = 3-F; R⁴ =4-F; R⁵ = 5-F phosphorous acid No. F.55 R¹ = CHF₂; R² = F; R³ = 3-F; R⁴= 4-F; R⁵ = 5-F phosphorous acid No. F.56 R¹ = CHF₂; R² = Cl; R³ = 3-F;R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.57 R¹ = CF₂Cl; R² = H; R³ =3-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.58 R¹ = CF₃; R² = H; R³ =3-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.59 R¹ = CF₃; R² = F; R³ =3-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.60 R¹ = CF₃; R² = Cl; R³= 3-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.61 R¹ = CH₃; R² = H; R³= 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.62 R¹ = CH₃; R² = F; R³= 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.63 R¹ = CH₃; R² = Cl;R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.64 R¹ = CH₂F; R² =H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.65 R¹ = CHFCl; R²= H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.66 R¹ = CHF₂;R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.67 R¹ =CHF₂; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.68 R¹= CHF₂; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No. F.69R¹ = CF₂Cl; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No.F.70 R¹ = CF₃; R² = H; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No.F.71 R¹ = CF₃; R² = F; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid No.F.72 R¹ = CF₃; R² = Cl; R³ = 2-F; R⁴ = 4-F; R⁵ = 5-F phosphorous acid

TABLE 9 Active compound combinations of compounds I with two activecompounds II: Active compound Active compound Mixture Compound of theformula I II II I-II-II.1 N-(2′-fluoro-4′-chloro-5′-methyl-pyraclostrobin epoxiconazole biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.2N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin epoxiconazole1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.3N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin epoxiconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.4N-(2′,4′-5′-trifluorobiphenyl-2-yl)- pyraclostrobin epoxiconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.5N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin epoxiconazole3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.6N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin metconazolebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.7 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetconazole 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.8 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.9 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.10 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetconazole 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.11 N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobintriticonazole biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.12 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin triticonazole 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.13 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin triticonazole 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.14 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin triticonazole 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.15 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin triticonazole 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.16 N-(2′-fluoro-4′-chloro-5′-methyl-pyraclostrobin fluquinconazole biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.17N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin fluquinconazole1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.18N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin fluquinconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.19N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin fluquinconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.20N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin fluquinconazole3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.21N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin prothioconazolebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.22 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinprothioconazole 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.23 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinprothioconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.24 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinprothioconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.25 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinprothioconazole 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.26 N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin tebuconazolebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.27 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobintebuconazole 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.28 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobintebuconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.29 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobintebuconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.30 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobintebuconazole 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.31 N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.32 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobincarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.33 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobincarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.34 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobincarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.35 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobincarbendazim 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.36 N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin thiophanate-biphenyl-2-yl)-1-methyl-3- methyl trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.37 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin thiophanate- 1-methyl-3-trifluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.38 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.39 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.40 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-pyraclostrobin thiophanate- 3-chlorofluoromethyl-1-methyl- methyl1H-pyrazole-4-carboxamide I-II-II.41 N-(2′-fluoro-4′-chloro-5′-methyl-pyraclostrobin benomyl biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.42N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.43N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.44N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.45N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobin benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.46N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.47 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinfenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.48 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinfenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.49 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinfenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.50 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinfenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.51 N-(2′-fluoro-4′-chloro-5′-methyl- pyraclostrobin metrafenonebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.52 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetrafenone 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.53 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.54 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.55 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- pyraclostrobinmetrafenone 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.56 N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methylepoxiconazole biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.57 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl epoxiconazole 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.58 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl epoxiconazole 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.59 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl epoxiconazole 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.60 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl epoxiconazole 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.61 N-(2′-fluoro-4′-chloro-5′-methyl-kresoxim-methyl metconazole biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.62N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl metconazole1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.63N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl metconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.64N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl metconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.65N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl metconazole3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.66N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methyl triticonazolebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.67 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltriticonazole 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.68 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltriticonazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.69 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltriticonazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.70 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltriticonazole 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.71 N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methylfluquinconazole biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.72 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl fluquinconazole 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.73 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl fluquinconazole 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.74 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl fluquinconazole 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.75 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl fluquinconazole 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.76 N-(2′-fluoro-4′-chloro-5′-methyl-kresoxim-methyl prothioconazole biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.77N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl prothioconazole1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.78N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl prothioconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.79N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl prothioconazole1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.80N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl prothioconazole3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.81N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methyl tebuconazolebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.82 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltebuconazole 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.83 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltebuconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.84 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltebuconazole 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.85 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyltebuconazole 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.86 N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methyl carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.87 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylcarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.88 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylcarbendazim 1-methyl-3-difluoromethyl-1H pyrazole-4-carboxamideI-II-II.89 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylcarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.90 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylcarbendazim 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.91 N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methylthiophanate- biphenyl-2-yl)-1-methyl-3- methyltrifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.92N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl thiophanate-1-methyl-3-trifluoromethyl-1H- methyl pyrazole-4-carboxamide I-II-II.93N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl thiophanate-1-methyl-3-difluoromethyl-1H- methyl pyrazole-4-carboxamide I-II-II.94N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl thiophanate-1-methyl-3-difluoromethyl-1H- methyl pyrazole-4-carboxamide I-II-II.95N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl thiophanate-3-chlorofluoromethyl-1-methyl- methyl 1H-pyrazole-4-carboxamideI-II-II.96 N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methyl benomylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.97 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.98N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.99N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.100N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methyl benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.101N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methyl fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.102 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylfenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.103 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylfenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.104 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylfenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.105 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- kresoxim-methylfenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.106 N-(2′-fluoro-4′-chloro-5′-methyl- kresoxim-methylmetrafenone biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.107 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl metrafenone 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.108 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl metrafenone 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.109 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl metrafenone 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.110 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-kresoxim-methyl metrafenone 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.111 N-(2′-fluoro-4′-chloro-5′-methyl-epoxiconazole 5-chloro-7- biphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidine I-II-II.112N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole 5-chloro-7-1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.113N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.114 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole5-chloro-7- 1-methyl-3-difluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.115N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole 5-chloro-7-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.116N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.117 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolecarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.118 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.119 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.120 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolecarbendazim 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.121 N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole thiophanate-biphenyl-2-yl)-1-methyl-3- methyl trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.122 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-epoxiconazole thiophanate- 1-methyl-3-trifluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.123 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-epoxiconazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.124 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-epoxiconazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.125 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-epoxiconazole thiophanate- 3-chlorofluoromethyl-1-methyl- methyl1H-pyrazole-4-carboxamide I-II-II.126 N-(2′-fluoro-4′-chloro-5′-methyl-epoxiconazole benomyl biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.127N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.128N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.129N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.130N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.131N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.132 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolefenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.133 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.134 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.135 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolefenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.136 N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole metrafenonebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.137 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolemetrafenone 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.138 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolemetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.139 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolemetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.140 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolemetrafenone 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.141 N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole metalaxylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.142 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole metalaxyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.143N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.144N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide d I-II-II.145N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole metalaxyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.146N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole iprodionebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.147 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole iprodione1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.148N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.149N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.150N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazole iprodione3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.151N-(2′-fluoro-4′-chloro-5′-methyl- epoxiconazole pyrimethanilbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.152 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolepyrimethanil 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.153 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.154 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.155 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- epoxiconazolepyrimethanil 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.156 N-(2′-fluoro-4′-chloro-5′-methyl- metconazole 5-chloro-7-biphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidine I-II-II.157N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole 5-chloro-7-1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.158N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.159 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.160 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole 5-chloro-7-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.161N-(2′-fluoro-4′-chloro-5′-methyl- metconazole carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.162 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole carbendazim1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.163N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole carbendazim1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.164N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazole carbendazim1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.165N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole carbendazim3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.166N-(2′-fluoro-4′-chloro-5′-methyl- metconazole thiophanate-biphenyl-2-yl)-1-methyl-3- methyl trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.167 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-metconazole thiophanate- 1-methyl-3-trifluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.168 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-metconazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.169 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-metconazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.170 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-metconazole thiophanate- 3-chlorofluoromethyl-1-methyl- methyl1H-pyrazole-4-carboxamide I-II-II.171 N-(2′-fluoro-4′-chloro-5′-methyl-metconazole benomyl biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.172N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.173N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.174N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.175N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.176N-(2′-fluoro-4′-chloro-5′-methyl- metconazole fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.177 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazolefenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.178 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.179 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.180 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazolefenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.181 N-(2′-fluoro-4′-chloro-5′-methyl- metconazole metrafenonebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.182 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metrafenone1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.183N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metrafenone1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.184N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metrafenone1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.185N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metrafenone3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.186N-(2′-fluoro-4′-chloro-5′-methyl- metconazole metalaxylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.187 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metalaxyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.188N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.189N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.190N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole metalaxyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.191N-(2′-fluoro-4′-chloro-5′-methyl- metconazole iprodionebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.192 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole iprodione1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.193N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.194N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.195N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazole iprodione3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.196N-(2′-fluoro-4′-chloro-5′-methyl- metconazole pyrimethanilbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.197 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazolepyrimethanil 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.198 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.199 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- metconazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.200 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- metconazolepyrimethanil 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.201 N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole 5-chloro-7-biphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidine I-II-II.202N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole 5-chloro-7-1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.203N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.204 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole5-chloro-7- 1-methyl-3-difluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.205N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole 5-chloro-7-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.206N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.207 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolecarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.208 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.209 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.210 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolecarbendazim 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.211 N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole thiophanate-biphenyl-2-yl)-1-methyl-3- methyl trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.212 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-triticonazole thiophanate- 1-methyl-3-trifluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.213 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-triticonazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.214 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-triticonazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.215 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-triticonazole thiophanate- 3-chlorofluoromethyl-1-methyl- methyl1H-pyrazole-4-carboxamide I-II-II.216 N-(2′-fluoro-4′-chloro-5′-methyl-triticonazole benomyl biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.217N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.218N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.219N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide id I-II-II.220N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.221N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.222 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolefenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.223 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.224 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.225 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolefenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.226 N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole metrafenonebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.227 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolemetrafenone 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.228 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolemetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.229 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolemetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.230 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolemetrafenone 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.231 N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole metalaxylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.232 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole metalaxyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.233N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.234N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.235N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole metalaxyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.236N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole iprodionebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.237 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole iprodione1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.238N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.239N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.240N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazole iprodione3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.241N-(2′-fluoro-4′-chloro-5′-methyl- triticonazole pyrimethanilbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.242 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolepyrimethanil 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.243 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.244 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- triticonazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.245 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolepyrimethanil 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.246 N-(2′-fluoro-4′-chloro-5′-methyl- fluquinconazole5-chloro-7- biphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidine I-II-II.247N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole 5-chloro-7-1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.248N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.249 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole5-chloro-7- 1-methyl-3-difluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.250N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole 5-chloro-7-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.251N-(2′-fluoro-4′-chloro-5′-methyl- fluquinconazole carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.252 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolecarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.253 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.254 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.266 N-(2′-fluoro-4′-chloro-5′-methyl- fluquinconazolefenpropimorph biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.267 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole fenpropimorph 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.268 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole fenpropimorph 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.269 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole fenpropimorph 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.270 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole fenpropimorph 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.271 N-(2′-fluoro-4′-chloro-5′-methyl-fluquinconazole metrafenone biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.272N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole metrafenone1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.273N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole metrafenone1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.274N-(2′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole metrafenone1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.275N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazole metrafenone3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.276N-(2′-fluoro-4′-chloro-5′-methyl- fluquinconazole metalaxylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.277 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolemetalaxyl 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.278 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolemetalaxyl 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.279 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolemetalaxyl 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.280 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazolemetalaxyl 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.281 N-(2′-fluoro-4′-chloro-5′-methyl- fluquinconazole iprodionebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.282 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazoleiprodione 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.283 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazoleiprodione 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.284 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazoleiprodione 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.285 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- fluquinconazoleiprodione 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.286 N-(2′-fluoro-4′-chloro-5′-methyl- fluquinconazolepyrimethanil biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.287 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole pyrimethanil 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.288 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole pyrimethanil 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.289 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole pyrimethanil 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.290 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-fluquinconazole pyrimethanil 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.291 N-(2′-fluoro-4′-chloro-5′-methyl-prothioconazole 5-chloro-7- biphenyl-2-yl)-1-methyl-3-(4-methylpiperidin- trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri-4-carboxamide fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.292 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole5-chloro-7- 1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.293N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.294 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole5-chloro-7- 1-methyl-3-difluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.295N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole 5-chloro-7-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.296N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazole carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.297 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolecarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.298 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.299 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.300 N-(3,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolecarbendazim 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.301 N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazolethiophanate- biphenyl-2-yl)-1-methyl-3- methyltrifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.302N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole thiophanate-1-methyl-3-trifluoromethyl-1H- methyl pyrazole-4-carboxamide I-II-II.303N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole thiophanate-1-methyl-3-difluoromethyl-1H- methyl pyrazole-4-carboxamide I-II-II.304N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole thiophanate-1-methyl-3-difluoromethyl-1H- methyl pyrazole-4-carboxamide I-II-II.305N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole thiophanate-3-chlorofluoromethyl-1-methyl- methyl 1H-pyrazole-4-carboxamideI-II-II.306 N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazole benomylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.307 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.308N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.309N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.310N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.311N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazole fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.312 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolefenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.313 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.314 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.315 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazolefenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.316 N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazolemetrafenone biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.317 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole metrafenone 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.318 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole metrafenone 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.319 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole metrafenone 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.320 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole metrafenone 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.321 N-(2′-fluoro-4′-chloro-5′-methyl-prothioconazole metalaxyl biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.322N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole metalaxyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.323N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.324N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.325N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazole metalaxyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.326N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazole iprodionebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.327 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazoleiprodione 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.328 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazoleiprodione 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.329 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazoleiprodione 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.330 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- prothioconazoleiprodione 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.331 N-(2′-fluoro-4′-chloro-5′-methyl- prothioconazolepyrimethanil biphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.332 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole pyrimethanil 1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.333 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole pyrimethanil 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.334 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole pyrimethanil 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide I-II-II.335 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-prothioconazole pyrimethanil 3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide I-II-II.336 N-(2′-fluoro-4′-chloro-5′-methyl-tebuconazole 5-chloro-7- biphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidine I-II-II.337N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole 5-chloro-7-1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.338N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole 5-chloro-7-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.339 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole5-chloro-7- 1-methyl-3-difluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.340N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole 5-chloro-7-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo[1,5- a]pyrimidine I-II-II.341N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole carbendazimbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.342 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolecarbendazim 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.343 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.344 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolecarbendazim 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.345 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolecarbendazim 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.346 N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole thiophanate-biphenyl-2-yl)-1-methyl-3- methyl trifluoromethyl-1H-pyrazole-4-carboxamide I-II-II.347 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-tebuconazole thiophanate- 1-methyl-3-trifluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.348 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-tebuconazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.349 N-(2′,4′,5′-trifluorobiphenyl-2-yl)-tebuconazole thiophanate- 1-methyl-3-difluoromethyl-1H- methylpyrazole-4-carboxamide I-II-II.350 N-(3′,4′,5′-trifluorobiphenyl-2-yl)-tebuconazole thiophanate- 3-chlorofluoromethyl-1-methyl- methyl1H-pyrazole-4-carboxamide I-II-II.351 N-(2′-fluoro-4′-chloro-5′-methyl-tebuconazole benomyl biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole- 4-carboxamide I-II-II.352N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole benomyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.353N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.354N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole benomyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.355N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole benomyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.356N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole fenpropimorphbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.357 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolefenpropimorph 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.358 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.359 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolefenpropimorph 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.360 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolefenpropimorph 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.361 N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole metrafenonebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.362 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolemetrafenone 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.363 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolemetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.364 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolemetrafenone 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.365 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolemetrafenone 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.366 N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole metalaxylbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.367 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole metalaxyl1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.368N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.369N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole metalaxyl1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.370N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole metalaxyl3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.371N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole iprodionebiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.372 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole iprodione1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamide I-II-II.373N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.374N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole iprodione1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamide I-II-II.375N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazole iprodione3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamide I-II-II.376N-(2′-fluoro-4′-chloro-5′-methyl- tebuconazole pyrimethanilbiphenyl-2-yl)-1-methyl-3- trifluoromethyl-1H-pyrazole- 4-carboxamideI-II-II.377 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolepyrimethanil 1-methyl-3-trifluoromethyl-1H- pyrazole-4-carboxamideI-II-II.378 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.379 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolepyrimethanil 1-methyl-3-difluoromethyl-1H- pyrazole-4-carboxamideI-II-II.380 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- tebuconazolepyrimethanil 3-chlorofluoromethyl-1-methyl- 1H-pyrazole-4-carboxamideI-II-II.381 N-(2′-fluoro-4′-chloro-5′-methyl- 5-chloro-7- carbendazimbiphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.382N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- carbendazim1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.383N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- carbendazim1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidineI-II-II.384 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- carbendazim1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidineI-II-II.385 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- carbendazim3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.386N-(2′-fluoro-4′-chloro-5′-methyl- 5-chloro-7- thiophanate-biphenyl-2-yl)-1-methyl-3- (4-methylpiperidin- methyltrifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.387N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- thiophanate-1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin- methylpyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.388N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- thiophanate-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- methylpyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.389N-(2′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- thiophanate-1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- methylpyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.390N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- thiophanate-3-chlorofluoromethyl-1-methyl- (4-methylpiperidin- methyl1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.391N-(2′-fluoro-4′-chloro-5′-methyl- 5-chloro-7- benomylbiphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.392N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- benomyl1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.393N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- benomyl1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidineI-II-II.394 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- benomyl1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidineI-II-II.395 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- benomyl3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.396N-(2′-fluoro-4′-chloro-5′-methyl- 5-chloro-7- fenpropimorphbiphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.397N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- fenpropimorph1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.398N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- fenpropimorph1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo[1,5- a]pyrimidineI-II-II.399 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7-fenpropimorph 1-methyl-3-difluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.400N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- fenpropimorph3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.401N-(2′-fluoro-4′-chloro-5′-methyl- 5-chloro-7- metrafenonebiphenyl-2-yl)-1-methyl-3- (4-methylpiperidin-trifluoromethyl-1H-pyrazole- 1-yl)-6-(2,4,6-tri- 4-carboxamidefluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.402N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- metrafenone1-methyl-3-trifluoromethyl-1H- (4-methylpiperidin-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine I-II-II.403N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- metrafenone1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidineI-II-II.404 N-(2′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- metrafenone1-methyl-3-difluoromethyl-1H- (4-methylpiperidin- pyrazole-4-carboxamide1-yl)-6-(2,4,6-tri- fluorophenyl)- [1,2,4]triazolo- [1,5-a]pyrimidineI-II-II.405 N-(3′,4′,5′-trifluorobiphenyl-2-yl)- 5-chloro-7- metrafenone3-chlorofluoromethyl-1-methyl- (4-methylpiperidin-1H-pyrazole-4-carboxamide 1-yl)-6-(2,4,6-tri- fluorophenyl)-[1,2,4]triazolo- [1,5-a]pyrimidine

The mixtures of compound(s) I and at least one of the active compoundsII, or at least one compound I and at least one of the active compoundsII applied simultaneously, that is jointly or separately, have excellentactivity against a broad spectrum of phytopathogenic fungi, inparticular from the class of the Ascomycetes, Basidiomycetes,Deuteromycetes and Peronosporomycetes (syn. Oomycetes). Some of them aresystemically effective and can be employed in crop protection as foliarfungicides, as fungicides for seed dressing and as soil fungicides. Theycan also be used for treating seed.

They are particularly important in the control of a multitude of fungion various cultivated plants, such as wheat, rye, barley, oats, rice,corn, lawns, bananas, cotton, soybean, coffee, sugar cane, grapevines,fruits and ornamental plants, and vegetables such as cucumbers, beans,tomatoes, potatoes and cucurbits, and on the seeds of these plants.

They are especially suitable for controlling the following plantdiseases:

-   -   Alternaria species on vegetables, oilseed rape, sugar beet and        fruit and rice, for example, A. solani or A. alternata on        potatoes and tomatoes;    -   Aphanomyces species on sugar beet and vegetables;    -   Ascochyta species on cereals and vegetables;    -   Bipolaris and Drechslera species on corn, cereals, rice and        lawns, for example, D. maydis on corn;    -   Blumeria graminis (powdery mildew) on cereals;    -   Botlytis cinerea (gray mold) on strawberries, vegetables,        flowers and grapevines;    -   Bremia lactucae on lettuce;    -   Cercospora species on corn, soybeans, rice and sugar beet;    -   Cochliobolus species on corn, cereals, rice, for example        Cochliobolus sativus on cereals, Cochliobolus miyabeanus on        rice;    -   Colletotricum species on soybeans and cotton;    -   Drechslera species, Pyrenophora species on corn, cereals, rice        and lawns, for example, D. teres on barley or D.        tritici-repentis on wheat;    -   Esca on grapevines, caused by Phaeoacremonium chlamydosporium,        Ph. Aleophilum and Formitipora punctata (syn. Phellinus        punctatus),    -   Exserohilum species on corn;    -   Erysiphe cichoracearum and Sphaerotheca fuliginea on cucumbers;    -   Fusarium and Verticillium species on various plants, for        example, F graminearum or F. culmorum on cereals or F. oxysporum        on a multitude of plants, such as, for example, tomatoes;    -   Gaeumanomyces graminis on cereals;    -   Gibberella species on cereals and rice (for example Gibberella        fujikuroi on rice);    -   Grainstaining complex on rice;    -   Helminthosporium species on corn and rice;    -   Michrodochium nivale on cereals;    -   Mycosphaerella species on cereals, bananas and peanuts, for        example, M. graminicola on wheat or M. fijiensis on bananas;    -   Peronospora species on cabbage and bulbous plants, for        example, P. brassicae on cabbage or P. destructor on onions;    -   Phakopsara pachyrhizi and Phakopsara meibomiae on soybeans;    -   Phomopsis species on soybeans and sunflowers;    -   Phytophthora infestans on potatoes and tomatoes;    -   Phytophthora species on various plants, for example, P. capsici        on bell pepper;    -   Plasmopara viticola on grapevines;    -   Podosphaera leucotricha on apples;    -   Pseudocercosporella herpotrichoides on cereals;    -   Pseudoperonospora on various plants, for example, P. cubensis on        cucumber or P. humili on hops;    -   Puccinia species on various plants, for example, P.        triticina, P. striformins, P., hordei or P. graminis on cereals        or P. asparagi on asparagus;    -   Pyrlcularia oryzae, Corticium sasakii, Sarocladium oryzae, S.        attenuatum, Entyloma oryzae on rice;    -   Pyricularia grisea on lawns and cereals;    -   Pythium spp. on lawns, rice, corn, cotton, oilseed rape,        sunflowers, sugar beet, vegetables and other plants, for        example, P. ultiumum on various plants, P. aphanidermatum on        lawns;    -   Rhizoctonia species on cotton, rice, potatoes, lawns, corn,        oilseed rape, sugar beet, vegetables and on various plants, for        example, R. solani on beet and various plants;    -   Rhynchosporium secalis on barley, rye and triticale;    -   Sclerotinia species on oilseed rape and sunflowers;    -   Septoria tritici and Stagonospora nodorum on wheat;    -   Erysiphe (syn. Uncinula) necator on grapevines;    -   Setospaeria species on corn and lawns;    -   Sphacelotheca reilinia on corn;    -   Thievaliopsis species on soybeans and cotton;    -   Tilletia species on cereals;    -   Ustilago species on cereals, corn and sugar cane, for        example, U. maydis on corn;    -   Venturia species (scab) on apples and pears, for example, V.        inaequalis on apples.

The mixtures according to the invention are also suitable forcontrolling harmful fungi in the protection of materials (for examplewood, paper, paint dispersions, fibers or fabrics) and in the protectionof stored products. In the protection of wood, particular attention ispaid to the following harmful fungi: Ascomycetes, such as Ophiostomaspp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp.,Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp.;Basidiomycetes, such as Coniophora spp., Coriolus spp., Gloeophyllumspp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. andTyromyces spp., Deuteromycetes, such as Aspergillus spp., Cladosporiumspp., Penicillium spp., Trichoderma spp., Alternaria spp., Paecilomycesspp. and Zygomycetes, such as Mucor spp., additionally in the protectionof materials the following yeasts: Candida spp. and Saccharomycescerevisae.

The compound(s) I and at least one of the active compounds II can beapplied simultaneously, that is jointly or separately, or in succession,the sequence, in the case of separate application, generally not havingany effect on the result of the control measures.

When preparing the mixtures, it is preferred to employ the pure activecompounds I and II, to which further compounds active against harmfulfungi or other pests, such as insects, arachnids or nematodes, or elseherbicidal or growth-regulating active compounds or fertilizers can beadded.

Such mixtures of three active compounds comprise, for example, acompound of the formula I, in particularN-(2′-fluoro-4′-chloro-5′-methylbiphenyl-2-yl)-1-methyl-3-trifluoro-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-1-methyl-3-tri-fluoromethyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamideorN-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,an azole from group A), in particular epoxiconazole, metconazole,triticonazole or fluquinconazole, and an insecticide, suitableinsecticides being in particular fipronil and neonicotinoids, such asacetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram,thiacloprid and thiamethoxam.

Usually, mixtures of at least one compound I and at least one activecompound II are employed. However, mixtures of at least one compound Iwith two or, if desired, more active components may also offerparticular advantages.

Suitable further active components in the above sense are particularlythe active compounds II mentioned at the outset and in particular thepreferred active compounds II mentioned above.

Compound(s) I and active compound(s) II are usually employed in a weightratio of from 100:1 to 1:100, preferably from 20:1 to 1:20, inparticular from 10:1 to 1:10.

The further active components are, if desired, mixed in a ratio of from20:1 to 1:20 to the compound I.

Depending on the type of the compounds I and II and the desired effect,the application rates of the mixtures according to the invention,especially on agricultural crop areas, are from 5 g/ha to 2000 g/ha,preferably from 20 to 1500 g/ha, in particular from 50 to 1000 g/ha.

Correspondingly, the application rates for the compound(s) I aregenerally from 1 to 1000 g/ha, preferably from 10 to 900 g/ha, inparticular from 20 to 750 g/ha.

Correspondingly, the application rates for the active compound II aregenerally from 1 to 2000 g/ha, preferably from 10 to 1500 g/ha, inparticular from 40 to 1000 g/ha.

In the treatment of seed, application rates of mixture are generallyfrom 1 to 1000 g per 100 kg of seed, preferably from 1 to 750 g per 100kg, in particular from 5 to 500 g per 100 kg of seed.

The method for controlling harmful fungi is carried out by the separateor joint application of compound(s) I and at least one of the activecompounds II, or a mixture of compound(s) I and at least one of theactive compounds II, by spraying or dusting the seeds, the plants or thesoils before or after sowing of the plants or before or after emergenceof the plants.

The fungicidal mixtures according to the invention, or the compound(s) Iand at least one of the active compounds II, can be converted into thecustomary formulations, for example solutions, emulsions, suspensions,dusts, powders, pastes and granules. The use form depends on theparticular intended purpose; in each case, it should ensure as fine andeven a distribution of the mixture according to the invention aspossible.

The formulations are prepared in a manner known per se, for example byextending the active compounds with solvents and/or carriers, if desiredusing emulsifiers and dispersants. Solvents/auxiliaries suitable forthis purpose are essentially:

-   -   water, aromatic solvents (for example Solvesso® products,        xylene), paraffins (for example mineral oil fractions), alcohols        (for example methanol, butanol, pentanol, benzyl alcohol),        ketones (for example cyclohexanone, gamma-butyrolactone),        pyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone), acetates        (glycol diacetate), glycols, fatty acid dimethylamides, fatty        acids and fatty acid esters. In principle, solvent mixtures may        also be used.    -   carriers such as ground natural minerals (for example kaolins,        clays, talc, chalk) and ground synthetic minerals (for example        highly disperse silica, silicates); emulsifiers such as        nonionogenic and anionic emulsifiers (for example        polyoxyethylene fatty alcohol ethers, alkylsulfonates and        arylsulfonates) and dispersants such as lignosulfite waste        liquors and methylcellulose.

Suitable surfactants used are alkali metal, alkaline earth metal andammonium salts of lignosulfonic acid, naphthalenesulfonic acid,phenolsulfonic acid, dibutylnaphthalenesulfonic acid,alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcoholsulfates, fatty acids and sulfated fatty alcohol glycol ethers,furthermore condensates of sulfonated naphthalene and naphthalenederivatives with formaldehyde, condensates of naphthalene or ofnaphthalenesulfonic acid with phenol and formaldehyde, polyoxy-ethyleneoctylphenyl ether, ethoxylated isooctylphenol, octylphenol, nonylphenol,alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether,tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcoholand fatty alcohol ethylene oxide condensates, ethoxylated castor oil,polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, laurylalcohol polyglycol ether acetal, sorbitol esters, lignosulfite wasteliquors and methylcellulose.

Substances which are suitable for the preparation of directly sprayablesolutions, emulsions, pastes or oil dispersions are mineral oilfractions of medium to high boiling point, such as kerosene or dieseloil, furthermore coal tar oils and oils of vegetable or animal origin,aliphatic, cyclic and aromatic hydrocarbons, for example toluene,xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or theirderivatives, methanol, ethanol, propanol, butanol, cyclohexanol,cyclohexanone, isophorone, highly polar solvents, for example dimethylsulfoxide, N-methylpyrrolidone and water.

Powders, materials for spreading and dustable products can be preparedby mixing or concomitantly grinding the active substances with at leastone solid carrier.

Granules, for example coated granules, impregnated granules andhomogeneous granules, can be prepared by binding the active compounds toat least one solid carrier. Examples of solid carriers are mineralearths such as silica gels, silicates, talc, kaolin, attaclay,limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth,calcium sulfate, magnesium sulfate, magnesium oxide, ground syntheticmaterials, fertilizers such as ammonium sulfate, ammonium phosphate,ammonium nitrate, ureas, and products of vegetable origin, such ascereal meal, tree bark meal, wood meal and nutshell meal, cellulosepowders and other solid carriers.

In general, the formulations comprise from 0.01 to 95% by weight,preferably from 0.1 to 90% by weight, of the compound(s) I and at leastone of the active compounds II or the mixture of compound(s) I with atleast one of the active compounds II. The active compounds are employedin a purity of from 90% to 100%, preferably 95% to 100% (according toNMR or HPLC spectrum).

The following are examples of formulations: 1. Products for dilutionwith water

A) Water-Soluble Concentrates (SL)

10 parts by weight of a mixture according to the invention are dissolvedin 90 parts by weight of water or in a water-soluble solvent. As analternative, wetting agents or other auxiliaries are added. The activecompounds dissolve upon dilution with water. In this way, a formulationhaving a total content of 10% by weight of active compound is obtained.

B) Dispersible Concentrates (DC)

20 parts by weight of a mixture according to the invention are dissolvedin 70 parts by weight of cyclohexanone with addition of 10 parts byweight of a dispersant, for example polyvinylpyrrolidone. Dilution withwater gives a dispersion. The active compound content is 20% by weight

C) Emulsifiable Concentrates (EC)

15 parts by weight of a mixture according to the invention are dissolvedin 75 parts by weight of xylene with addition of calciumdodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 partsby weight). Dilution with water gives an emulsion. The formulation hasan active compound content of 15% by weight.

D) Emulsions (EW, EO)

25 parts by weight of a mixture according to the invention are dissolvedin 35 parts by weight of xylene with addition of calciumdodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 partsby weight). This mixture is introduced into 30 parts by weight of waterby means of an emulsifying machine (e.g. Ultraturrax) and made into ahomogeneous emulsion. Dilution with water gives an emulsion. Theformulation has an active compound content of 25% by weight.

E) Suspensions (SC, OD)

In an agitated ball mill, 20 parts by weight of a mixture according tothe invention are comminuted with addition of 10 parts by weight ofdispersants and wetting agents and 70 parts by weight of water or anorganic solvent to give a fine active compound suspension. Dilution withwater gives a stable suspension of the active compounds. The activecompound content in the formulation is 20% by weight.

F) Water-Dispersible Granules and Water-Soluble Granules (WG, SG)

50 parts by weight of a mixture according to the invention are groundfinely with addition of 50 parts by weight of dispersants and wettingagents and prepared as water-dispersible or water-soluble granules bymeans of technical appliances (for example extrusion, spray tower,fluidized bed). Dilution with water gives a stable dispersion orsolution of the active compounds. The formulation has an active compoundcontent of 50% by weight.

G) Water-Dispersible Powders and Water-Soluble Powders (WP, SP)

75 parts by weight of a mixture according to the invention are ground ina rotor-stator mill with addition of 25 parts by weight of dispersants,wetting agents and silica gel. Dilution with water gives a stabledispersion or solution of the active compounds. The active compoundcontent of the formulation is 75% by weight.

2. Products to be Applied Undiluted

H) Dustable Powders (DP)

5 parts by weight of a mixture according to the invention are groundfinely and mixed intimately with 95 parts by weight of finely dividedkaolin. This gives a dustable product having an active compound contentof 5% by weight.

J) Granules (GR, FG, GG, MG)

0.5 part by weight of a mixture according to the invention is groundfinely and associated with 99.5 parts by weight of carriers. Currentmethods are extrusion, spray-drying or the fluidized bed. This givesgranules to be applied undiluted having an active compound content of0.5% by weight.

K) ULV Solutions (UL)

10 parts by weight of a mixture according to the invention are dissolvedin 90 parts by weight of an organic solvent, for example xylene. Thisgives a product to be applied undiluted having an active compoundcontent of 10% by weight.

The active compounds can be used as such, in the form of theirformulations or the use forms prepared therefrom, for example in theform of directly sprayable solutions, powders, suspensions ordispersions, emulsions, oil dispersions, pastes, dustable products,materials for spreading, or granules, by means of spraying, atomizing,dusting, spreading or pouring. The use forms depend entirely on theintended purposes; they are intended to ensure in each case the finestpossible distribution of the active compounds.

Aqueous use forms can be prepared from emulsion concentrates, pastes orwettable powders (sprayable powders, oil dispersions) by adding water.To prepare emulsions, pastes or oil dispersions, the substances, as suchor dissolved in an oil or solvent, can be homogenized in water by meansof a wetting agent, tackifier, dispersant or emulsifier. However, it isalso possible to prepare concentrates composed of active substance,wetting agent, tackifier, dispersant or emulsifier and, if appropriate,solvent or oil, and such concentrates are suitable for dilution withwater.

The active compound concentrations in the ready-to-use preparations canbe varied within relatively wide ranges. In general, they are from0.0001 to 10%, preferably from 0.01 to 1%.

The active compounds may also be used successfully in theultra-low-volume process (ULV), it being possible to apply formulationscomprising over 95% by weight of active compound, or even to apply theactive compound without additives.

Oils of various types, wetting agents, adjuvants, herbicides, other pestcontrol agents or bactericides may be added to the active compounds,even, if desired, not until immediately prior to use (tank mix). Theseagents are typically mixed with the mixtures according to the inventionin a weight ratio of from 1:100 to 100:1, preferably from 1:10 to 10:1.

Suitable adjuvants in this context are, in particular: organicallymodified polysiloxanes, e.g. Break Thru S 240®; alcohol alkoxylates,e.g. Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON30®; EO/PO block polymers, e.g. Pluronic RPE 2035® and Genapol B®;alcohol ethoxylates, e.g. Lutensol XP 80®; and sodiumdioctylsulfosuccinate, e.g. Leophen RA®.

The compounds I and II or the mixtures or the corresponding formulationsare applied by treating the harmful fungi, their habitat or the plants,seeds, soils, areas, materials or spaces to be kept free from them witha fungicidally effective amount of the mixture or, in the case ofseparate application, of the compounds I and II. Application can bebefore or after the infection by harmful fungi.

USE EXAMPLES

The fungicidal action of the individual compounds and of the mixturesaccording to the invention was demonstrated by the tests below.

The active compounds, separately or jointly, were prepared as a stocksolution comprising 25 mg of active compound which was made up to 10 mlusing a mixture of acetone and/or dimethyl sulfoxide and the emulsifierUniperol® EL (wetting agent having an emulsifying and dispersing actionbased on ethoxylated alkylphenols) in a ratio by volume ofsolvent/emulsifier of 99:1. The mixture was then made up to 100 ml withwater. This stock solution was diluted with the solvent/emulsifier/watermixture described to give the concentration of active compound statedbelow.

As an alternative, the active compounds epoxiconazole, triticonazole andpyraclostrobin were used as commercially available ready-to-useformulation and diluted to the specified active compound concentrationwith water.

The visually determined percentages of infected leaf areas wereconverted into efficacies in % of the untreated control:

The efficacy (E) is calculated as follows using Abbot's formula:E=(1−α/β)·100α corresponds to the fungicidal infection of the treated plants in % andβ corresponds to the fungicidal infection of the untreated (control)plants in %

An efficacy of 0 means that the infection level of the treated plantscorresponds to that of the untreated control plants; an efficacy of 100means that the treated plants are not infected.

The expected efficacies of active compound combinations were determinedusing Colby's formula (Colby, S. R. “Calculating synergistic andantagonistic responses of herbicide combinations”, Weeds, 15, 20-22,1967) and compared with the observed efficacies.

Colby's formula:E=x+y−x·y/100

-   E expected efficacy, expressed in % of the untreated control, when    using the mixture of the active compounds A and B at the    concentrations a and b;-   x efficacy, expressed in % of the untreated control, when using the    active compound A at the concentration a;-   y efficacy, expressed in % of the untreated control, when using the    active compound B at the concentration b.

Use Example 1 Activity Against Early Blight of Tomato Caused byAlternaria solani

Leaves of potted tomato plants were sprayed to runoff point with anaqueous suspension having the active compound concentration statedbelow. The next day, the leaves were infected with an aqueous sporesuspension of Alternaria solani in a 2% biomalt solution having adensity of 0.17×10⁶ spores/ml. The plants were then placed in a watervapor-saturated chamber at temperatures between 20 and 22° C. After 5days, the disease on the untreated but infected control plants haddeveloped to such an extent that the infection could be determinedvisually in %.

Activity Active Observed calculated compounds/active Concentrationactivity according to compound mixture [mg/l] Ratio (% infection) Colby(%) (Control) — — 0 (90% — infection) No. Ia.719  4 — 0 — prochloraz 16— 30 — pyraclostrobin  4 — 50 — metiram 63 — 0 — chlorthalonil 63 — 0 —No. Ia.719 + 4 + 16 1:4 60 30 prochloraz No. Ia.719 + 4 + 4  1:1 93 50pyraclostrobin No. Ia.719 + 4 + 63 1:4 70 0 metiram No. Ia.179 + 4 + 631:4 70 0 chlorthalonil

Use Example 2 Activity Against Gray Mold on Bell Pepper Leaves Caused byBotrytis cinerea, 1 Day of Protective Application

Bell pepper seedlings of the cultivar “Neusiedler Ideal Elite” were,after 2-3 leaves were well developed, sprayed to runoff point with anaqueous suspension in the active compound concentration specified below.The next day, the treated plants were inoculated with a spore suspensionof Botrytis cinerea which contained 1.7×10⁶ spores/ml in a 2% strengthaqueous biomalt solution. The test plants were then placed in aclimatized chamber at 22 to 24° C., darkness and high atmospherichumidity. After 5 days, the extent of the fungal infection on the leavescould be determined visually in %.

Activity Active Observed calculated compounds/active Concentrationactivity according to compound mixture [mg/l] Ratio (% infection) Colby(%) (Control) — — 0(100% — infection) No. Id.344 1 — 40 — No. Ia.344 16— 60 — No. Ij.344 4 — 22 — 1 — 0 — triticonazole 4 — 0 — prochloraz 4 —11 — dimethomorph 63 — 0 — 16 — 0 — 4 — 0 — metiram 16 — 0 — metrafenone63 — 0 — 16 — 0 — 4 — 0 — No. Id.344 + 1 + 4  1:4 80 40 dimethomorph No.Id.344 + 1 + 16  1:16 70 40 metiram No. Id.344 + 1 + 4  1:4 60 40metrafenone No. Ia.344 + 16 + 63 1:4 85 60 dimethomorph No. Ia.344 +16 + 63 1:4 90 60 metrafenone No. Ij.344 + 4 + 4  1:1 78 22triticonazole No. Ij.344 + 1 + 4  1:4 92 11 prochloraz No. Ij.344 + 4 +16 1:4 78 22 dimethomorph No. Ij.344 + 4 + 16 1:4 100 22 metrafenone

Use Example 3 Curative Activity Against Brown Rust of Wheat Caused byPuccinia recondita

Leaves of potted wheat seedlings of the cultivar “Kanzler” wereinoculated with a spore suspension of brown rust (Puccinia recondita).The pots were then placed in a chamber with high atmospheric humidity(90 to 95%) and 20 to 22° C. for 24 hours. During this time, the sporesgerminated and the germ tubes penetrated into the leaf tissue. The nextday, the infected plants were sprayed to runoff point with theabove-described active compound solution having the active compoundconcentration stated below. After the spray coating had dried on, thetest plants were cultivated in a greenhouse at temperatures between 20and 22° C. and 65 to 70% relative atmospheric humidity for 7 days. Theextent of the rust fungal development on the leaves was then determined.

Activity Active Observed calculated compounds/active Concentrationactivity according to compound mixture [mg/l] Ratio (% infection) Colby(%) (Control) — — 0 (90% — infection) No. Id.344 1 — 0 — No. Ij.344 1 —0 — No. Ia.719 0.25 — 0 — epoxiconazole 0.063 — 0 — triticonazole 1 — 0— pyraclostrobin 1 — 0 — chlorthalonil 16 — 0 — 5-chloro-7- 4 — 40 —(4-methyl- piperidin-1-yl)- 6-(2,4,6- trifluorophenyl)- [1,2,4]tri-azolo[1,5- a]pyrimidine No. Id.344 + 1 + 1 1:1 56 0 triticonazole No.Id.344 + 1 + 1 1:1 83 0 pyraclostrobin No. Id.344 +  1 + 16  1:16 78 0chlorthalonil No. Ij.344 + 1 + 4 1:4 100 40 5-chloro-7-(4-methylpiperidin- 1-yl)-6-(2,4,6- trifluorophenyl)- [1,2,4]tri-azolo[1,5- a]pyrimidine No. Ia.719 +  0.25 + 0.063 4:1 30 0epoxiconazole

Use Example 4 Activity Against Net Blotch of Barley Caused byPyrenophora teres, 1 Day Protective Application

Leaves of potted barley seedlings were sprayed to runoff point with anaqueous suspension having the active compound concentration statedbelow. 24 hours after the spray coating had dried on, the test plantswere inoculated with an aqueous spore suspension of Pyrenophora [syn.Drechslera] teres, the net blotch pathogen. The test plants were thenplaced in a greenhouse at temperatures between 20 and 24° C. and 95 to100% relative atmospheric humidity. After 6 days, the extent of thedevelopment of the disease was determined visually in % infection of theentire leaf area.

Activity Active Observed calculated compounds/active Concentrationactivity according to compound mixture [mg/l] Ratio (% infection) Colby(%) (Control) — — 0 (90% — infection) No. Id.344 0.25 — 67 —epoxiconazole 0.063 — 0 — No. Id.344 +  0.25 + 0.063 4:1 83 67epoxiconazole

The test results show that, by virtue of the synergism, the mixturesaccording to the invention are considerably more active than had beenpredicted using Colby's formula.

The invention claimed is:
 1. A fungicidal mixture comprising, 1) atleast one compound of formula I

wherein: X is oxygen; R¹ is C₁-C₄-alkyl or C₁-C₄-haloalkyl; R² ishydrogen; R³, R⁴ and R⁵ independently of one another are halogen; and 2)at least one active compound II selected from the group consisting of:A) bitertanol, bromuconazole, cyproconazole, difenoconazole,diniconazole, enilconazole, epoxiconazole, fluquinconazole,fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole,ipconazole, metconazole, myclobutanil, penconazole, propiconazole,prothioconazole, simeconazole, triadimefon, triadimenol, tebuconazole,tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil,triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole,fuberidazole, ethaboxam, etridiazole and hymexazole; B) azoxystrobin,dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl,methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin,trifloxystrobin, enestroburin, methyl(2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl(2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamateand methyl2-(ortho-(2,5-dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate; C)carboxin, benalaxyl, boscalid, fenhexamid, flutolanil, furametpyr,mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin,penthiopyrad, thifluzamide, tiadinil,3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide, dimethomorph,flumorph, flumetover, fluopicolide (picobenzamid), zoxamide,carpropamid, diclocymet, mandipropamid,N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide,N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide,methyl3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propionate,compounds of formula III

wherein: R⁴ of formula III is methyl or ethyl,N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide,N-(3′,4′-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamideand N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide; D)fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone,mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil,fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph,fenpropidin, iprodione, procymidone, vinclozolin, famoxadone,fenamidone, octhilinone, probenazole,5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine,anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, acompound of formula IV (2-butoxy-6-iodo-3-propylchromen-4-one)

acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil,quinoxyfen andN,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamideof formula V

E) mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb,ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb,4-fluorophenyl N-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)carbamate,methyl3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methyl-butyrylamino)propanoateof formula VI

and carbamate oxime ethers of formula VII

wherein: Z is N or CH; F) guanidine, dodine, iminoctadine, guazatine,kasugamycin, streptomycin, polyoxin, validamycin A, binapacryl, dinocap,dinobuton, dithianon, isoprothiolane, fentin salts, edifenphos,iprobenfos, fosetyl, fosetyl-aluminum, phosphorous acid and its salts,pyrazophos, tolclofos-methyl, chlorothalonil, dichlofluanid,flusulfamide, hexachlorobenzene, phthalide, pencycuron, quintozene,thiophanate-methyl, tolylfluanid, Bordeaux mixture, copper acetate,copper hydroxide, copper oxychloride, basic copper sulfate, sulfur,cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenoneand spiroxamine; wherein the at least one compound of formula I and theat least one active compound II are present in a synergisticallyeffective amount.
 2. The fungicidal mixture of claim 1, wherein the atleast one compound I is selected from the group consisting of:N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1methyl-1H-pyrazole-4-carboxamide andN-(2′,4′,5′-trifluorobiphenyl-2-yl)-3fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.
 3. The fungicidalmixture of claim 1, wherein the at least one compound of formula I andthe at least one active compound II are present in a weight ratio offrom 100:1 to 1:100.
 4. The fungicidal mixture of claim 1, wherein theat least one compound of formula I and the at least one active compoundII are present in a weight ratio of from 100:1 to 1:100.
 5. Thefungicidal mixture of claim 2, wherein the at least one compound offormula I and the at least one active compound II are present in aweight ratio of from 100:1 to 1:100.
 6. The fungicidal mixture of claim1, further comprising at least one liquid or solid carrier.
 7. Thefungicidal mixture of claim 1, further comprising at least one liquid orsolid carrier.
 8. The fungicidal mixture of claim 2, further comprisingat least one liquid or solid carrier.
 9. A method for controllingphytopathogenic harmful fungi comprising, contacting fungi, theirhabitat or the plants, soil, seeds, areas, materials or spaces to beprotected against fungal attack with a fungicidal mixture of claim 1,wherein the at least one compound of formula I and the at least oneactive compound II are present in a synergistically effective amount;wherein phytopathogenic harmful fungi are controlled.
 10. The method ofclaim 9, wherein the at least one compound of formula I and the at leastone active compound II are applied simultaneously, separately, or insuccession.
 11. The method of claim 9, wherein the at least one compoundof formula I and the at least one active compound II are applied in anamount of from 5 g/ha to 2000 g/ha.
 12. The method of claim 9, whereinthe at least one compound of formula I and the at least one activecompound II are applied in an amount of from 1 g to 1000 g per 100 kg ofseed.
 13. The method of claim 9, wherein the at least one compound I isselected from the group consisting of:N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1methyl-1H-pyrazole-4-carboxamide andN-(2′,4′,5′-trifluorobiphenyl-2-yl)-3fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.
 14. A seed, treatedwith a fungicidal mixture of claim 1, wherein the at least one compoundof formula I and the at least one active compound II are present in asynergistically effective amount.
 15. The seed of claim 14, wherein theat least one compound of formula I and the at least one active compoundII are present in an amount of from 1 g to 1000 g per 100 kg of seed.16. The seed of claim 14, wherein the at least one formula I is selectedfrom the group consisting of: N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,N-(2′,3′,4′-trifluorobiphenyl-2-yl)-3-fluoromethyl-1methyl-1H-pyrazole-4-carboxamide andN-(2′,4′,5′-trifluorobiphenyl-2-yl)-3fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide.